二次开模距离对微发泡聚丙烯材料发泡行为的影响.pdfVIP

理论与研 二次开模距离对微发泡聚丙烯材料发泡行为的影响 MoldDistance Behaviorof Effectof on Twice--open Micro--foaming Material PolyprOpylene 缫然一 括要 采用化学发治注望成墅技术，在二次开接条件下制鲁徽发泡聚丙蠕(PP)材料；通过热力学分析法研究了二次 开攥距离对PP徽发治材料发治行为的影响。结果寰明：二次开簟距离能有姓地控制PP材料的发治过程，二 次开模距离趁小．体系的发泡过程越窑易自发进行。当二次开囊臣lI￡=5．3mm时，伴系中的言布斯自由能 小于霉．发泡过程不可能自发进行一二次开攥距曩￡=4．3mm时．PP体系的发海质量■理想．港孔平均I经为 21．6 pm．泡孔密度为5．63x105个／cm3．能够获得泡孔细小．均匀的徽发治PP材辩。 Abstract chemicaIfoamIn口injection microceIIuIar foam BYtaking moIdingtechnoIogv。the weremadeundertheconditionof mold．Theeffectof poIvpropvIenefPP)materials twice-open different molddistanceon behaviorofPPmaterialswas means twice-open foaming analyzedby of TheresuItsshowthat molddistancecan thermodynamjcanalysis twice-open effectively ofPP control rocess smaller mold easier foamingp materials，thetwice-opendistance．the ofPP materials mold foamingprocess proceedspontaneousIy．Whentwice—opendistance但) is53 free AGisbelow the can’t mm．Gibbsenergy zero．andfoamingDrocessproceed Lis4．3 isanideaI effectinmicrocellularfoamPP spontaneously：whenmm．there foaming celldiameteris21．6 cell is thenthe materials．average pm，anddensity5．63×10。pcslcm4：and PPmaterialwithfineanduniform