太湖、洞庭湖野生青虾肌肉中有机氯农药的气相色谱-质谱法测定.pdfVIP

J. Lake Sci.(湖泊科学), 2009, 21(5): 631-636 . E-mail: jlakes@ ©2009 by Journal of Lake Sciences 太湖、洞庭湖野生青虾肌肉中有机氯农药的气相色谱-质谱法测定*1 1 2 1 1 1 1 史双昕, 卢婉云 , 邵丁丁 , 周 丽 , 张 烃 , 黄业茹 (1: 国家环境分析测试中心, 国家环境保护二噁英污染控制重点实验室, 北京 100029) (2: 中国人民大学环境学院, 北京 100081) 摘 要: 使用气相色谱质谱技术测定了青虾肌肉组织中的8种有机氯农药, 包括六氯苯、氯丹、滴滴涕(∑DDTs) 、艾氏剂、狄 氏剂、异狄氏剂、七氯和灭蚁灵. 对太湖和洞庭湖15个点位29组野生青虾样品的测定结果显示, 青虾肌肉组织内残留的有机 氯农药主要是六氯苯和滴滴涕, 六氯苯含量为nd-13.2μg/kg(湿重), 滴滴涕含量为0.790-5.82μg/kg(湿重). 洞庭湖青虾肌肉中 有机氯农药的含量略高于太湖青虾, 两湖青虾肌肉残留有机氯农药在枯水期时的含量多数大于丰水期时的含量. 关键词: 气相色谱质谱法; 青虾; 有机氯农药; 太湖; 洞庭湖 Determination of organochlorine pesticides in wild shrimps muscle tissue in Lake Taihu and Lake Dongting by Gas Chromatogrphy/Mass Spectrometry 1 2 1 1 1 1 SHI Shuangxin , LU Wanyun , SHAO Dingding , ZHOU Li , ZHANG Ting HUANG Yeru (1: National Research Center for Environmental Analysis and Measurements , Dioxins Laboratory of the National Research Center for Environment Analysis and Measurement , Beijing 100029, P.R.China) (2: Environment College, Renmin University of China , Beijing 100081, P.R.China) Abstract : Twenty-nine shrimp samples from 15 sites in Lake Taihu and Lake Dongting were collected and measured, and 8 kinds of organochlorine pesticides (OCPs) in wild shrimps muscle tissue were analyzed with Gas Chromatography/Mass Spectrometry. Hexachlorobenzene(HCB), Chlordane, ∑DDTs(p,p ′-DDT、o,p′-DDT、p,p ′-DDE、o,p′-DDE、p,p ′-DDD、o,p′-DDD), Aldrin, Dieldrin, Endrin, Heptachlor and Mirex were quantified. The results showed HCB and p,p ′-DDE were detected widely in all shrimp samples. HCB residues in shrimp muscle ranged from nd to 13.2μg/kg and p ,p ′-DDE ranged from 0.790 to 5.82μg/kg. Much higher concentration of OCPs was found in shrimp’s muscle of Lake Taihu than