Optical properties of cobalt xanthate films on different substrates.pdfVIP

Optical properties of cobalt xanthate films on different substrates.pdf

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Optical properties of cobalt xanthate films on different substrates.pdf

InternationalJournalofMinerals,MetallurgyandMaterials Volume21,Number7.Ju/y2014,Page736 DOh10。1007/s12613-014-0965-y Opticalpropertiesofcobaltxanthatefilmsondifferentsubstrates I.A·.Kariper11、andTOzpozanL1、’ 1)EducationFaculty,ErciyesUniversiyt,Kayseri,Turkey 2)Che~stryDepartment,ScienceFaculyt,ErciyesUniversity,Kayseri,Turkey (Received:15November2013;revised:21Feburary2014;accepted:24February2014) Abstract:Cobaltisopropy1xanthatethinfilms(CXTFs)weredepositedviachemicalbathdepositionontodifferentsubstrates:commercial glass(CG),indiumtinoxide(ITO),andpoly(methylmethacrylate)(PMM).Isopropylxanthatewassynthesizedaccordingtoamehtodde- scribedni hteliterature.Thecobaltnitratena disopropylxanhtateweremixedinabeaker,whichallowedthehtinfilmstobedepositedviaa simpleion-ionmechanism.Thertansmission,reflectivity,refractiveindex,dielectricconstant,na dopticalconductivitywereinvestigatedfor varioushtinfilmscoatedontodifferentsubstrates.Anultraviolet.visiblespectrophotometerwasusedtomeas~etheopticalpropertiesofthe htinfiml s.Th e1owestvalueofhtetransmissionnadhtehighestvalueoftherefractivenidexwereobservedforhtethinfilmsdpeositedonto PⅣ蹦 .Thestruc~treofthecobaltxanhtatewascharacterizedbyFouriertransofrm infiared(FTIR)spectroscopy,whichwasmeasuredusing aPerkin-Emi erSpectrum 400spectrometer.ThesrtetchingvibrationoftheCo—Sbondswasobservedat359cm- nihteFTIR spectrum of theCXTFs. Keywords:htni films;cobaltcompounds;xnahtates;chemicaldeposition;opticalproperties 1.Introduction examinehtechangesintrna smissionnadreflectionproper- ties,refractionindices,extinctioncoefficients,na ddielectric Xanthatescaneasilyform compositeswithmetals.The constantsofthefilmsasftmctionsofincidentradiation preciFlitationofthemetalisinducedthroughhtecombina— wavelength. tionofliquidsolutions,whichresultinacompoundwith veryl

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