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Optical properties of cobalt xanthate films on different substrates.pdf
InternationalJournalofMinerals,MetallurgyandMaterials
Volume21,Number7.Ju/y2014,Page736
DOh10。1007/s12613-014-0965-y
Opticalpropertiesofcobaltxanthatefilmsondifferentsubstrates
I.A·.Kariper11、andTOzpozanL1、’
1)EducationFaculty,ErciyesUniversiyt,Kayseri,Turkey
2)Che~stryDepartment,ScienceFaculyt,ErciyesUniversity,Kayseri,Turkey
(Received:15November2013;revised:21Feburary2014;accepted:24February2014)
Abstract:Cobaltisopropy1xanthatethinfilms(CXTFs)weredepositedviachemicalbathdepositionontodifferentsubstrates:commercial
glass(CG),indiumtinoxide(ITO),andpoly(methylmethacrylate)(PMM).Isopropylxanthatewassynthesizedaccordingtoamehtodde-
scribedni hteliterature.Thecobaltnitratena disopropylxanhtateweremixedinabeaker,whichallowedthehtinfilmstobedepositedviaa
simpleion-ionmechanism.Thertansmission,reflectivity,refractiveindex,dielectricconstant,na dopticalconductivitywereinvestigatedfor
varioushtinfilmscoatedontodifferentsubstrates.Anultraviolet.visiblespectrophotometerwasusedtomeas~etheopticalpropertiesofthe
htinfiml s.Th e1owestvalueofhtetransmissionnadhtehighestvalueoftherefractivenidexwereobservedforhtethinfilmsdpeositedonto
PⅣ蹦 .Thestruc~treofthecobaltxanhtatewascharacterizedbyFouriertransofrm infiared(FTIR)spectroscopy,whichwasmeasuredusing
aPerkin-Emi erSpectrum 400spectrometer.ThesrtetchingvibrationoftheCo—Sbondswasobservedat359cm- nihteFTIR spectrum of
theCXTFs.
Keywords:htni films;cobaltcompounds;xnahtates;chemicaldeposition;opticalproperties
1.Introduction examinehtechangesintrna smissionnadreflectionproper-
ties,refractionindices,extinctioncoefficients,na ddielectric
Xanthatescaneasilyform compositeswithmetals.The constantsofthefilmsasftmctionsofincidentradiation
preciFlitationofthemetalisinducedthroughhtecombina— wavelength.
tionofliquidsolutions,whichresultinacompoundwith
veryl
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