城市污泥总氮、总磷.docVIP

文章编号(2010) 032099204 城市污泥总氮、总磷消解测定方法 陈大勇1 , 王里奥1 , 罗书鸾2 , 马培东1 , 陶　玉1 (1. 重庆大学资源及环境科学学院, 重庆400044 ;2. 中化重庆涪陵化工有限公司, 重庆408000) 收稿日期:2009210219 基金项目:重庆市市政管理委员会项目(Z200521255002) 作者简介:陈大勇(19732) ,男,重庆大学讲师,博士研究生,主要从事固体废弃物处理与资源化利用研究。 王里奥(联系人) ,女,重庆大学教授,博士生导师, (E2mail) wan@yahoo. com. cn。 摘　要:设计了正交实验并分析了H2O2 与H2 SO4 消解污泥过程影响因素,在测定总氮时 H2O2 添加次数在0. 1 水平下具有显著性,而H2O2 用量和H2 SO4 用量对总氮的测定影响较小,较 优的消解方案: H2O2 添加次数为3 次、每次消耗为0. 25 mL , H2 SO4 用量为1 mL ;在测定总磷时 H2O2 添加次数在0. 01 水平下具有显著性, H2O2 单次用量在0. 05 水平下具有显著性,而H2 SO4 用量对总氮的测定影响较小,较优的消解方案: H2O2 添加次数为3 次,每次消耗为0. 25 mL , H2 SO4 用量为5 mL 。综合考虑,总氮、总磷测定方法的最佳方案即H2O2 添加次数为3 次,每次消 耗为0. 25 mL ,H2 SO4 用量为5 mL 。按照该消解方案,测出总氮的回收率在98. 53 %～101. 80 % , 总磷的回收率在97. 07 %～101. 67 %。 关键词:污泥;总氮;总磷;消解;正交实验 　　中图分类号:X705 文献标志码:A A digesting measurement method of municipal sewage sludge’s TNand TP CHEN Da2yong1 , WANGLi2ao1 , LUO Shu2luan2 , MA Pei2dong1 , TAO Yu1 (1. College of Resources and Environmental Science , Chongqing University , Chongqing 400044 , P. R. China ; 2. SINOCHEM Fuling Chongqing Chemical Indust ry CO. , L TD. , Chongqing 408000 , P. R. China) Abstract : Paramet ric st udy wit h ort hogonal experiment is carried out for digestion of municipal sewage sludge with H2O2 and H2 SO4 . For TN , t he adding time of H2O2 is significant at 0. 1 level , whil st t he dosages of H2O2 and H2 SO4 are less significant . The bet ter digestion scheme is t hat the number of adding time of H2O2 is t hree and t he dosages of H2O2 and H2 SO4 are 0. 25 mL and 1 mL , respectively. And for TP , t he adding time of H2O2 is significant at 0. 01 level , and the dosage of H2O2 is significant at 0. 05 level. However , t he dosage of H2 SO4 is less significant . Thus , t he bet ter digestion scheme is t hat t he adding time of H2O2 is t hree and t he dosages of H2O2 and H2 SO4 are 0. 25 and 5mL , respectively. Combining t he two schemes , t he optimal scheme of sludge digestion is t hree times for H2O2 adding and 0. 25 and 5mL for t he dosages of H2O2