分散聚合法制备单分散聚苯乙烯微球.pdfVIP

Vol. 19-20 No. 2 # 172 # Journal of Functional Polym ers 2007 6 1 1 2 范 婷 , 陈建定 , 黄广建 ( 1. 华东理工大学材料科学与工程学院, 国家超细粉末工程研究中心, 上海200237; 2. 旦大学附属华山医院, 上海200040) : 以苯乙烯为单体, 偶氮二异 丁腈为引发剂, 聚乙烯吡咯烷酮为分散稳定剂, 在乙 醇/ 水的极性反应体系中, 使用分散聚合法制备了聚苯乙烯( PS) 微球研究了制备工艺对 微球分子量等远程结构参数的影响研究结果表明: 在适合微球形成的单体用量引发剂和 分散稳定剂的浓度反应温度时间和乙醇/ 水的比例等参数下, 克服了以往存在的粒径不均 匀分子量较低微球表面圆整光洁度较低和产率偏低等主要问题, 制备了粒径在 1. 5~ 3 4 Lm 之间粒径分布1. 05~ 1. 0 分子量 0 @ 10 左右最高得率达97%球体表面光洁球 形对称均匀且相互不粘连的单分散PS 微球 : 聚苯乙烯; 单分散; 粒径分布; 分散聚合; 微球形成机理 : O631 : A : 100-9357( 2007)-0172-06 Preparation of Monodispersed Polystyrene Microspheres by Dispersion Polymerization 1 1 2 FAN T ing , CHEN Jian-ding , HUA NG Guang-jian ( 1. School of M aterials Science and Engineering, National Engineering Research Center of Ultrafine Pow der, East China U niversity of Science and Technology, Shanghai 200237, China; 2. Huashan Hospital Affiliated to Fudan U niversity , Shanghai 200040, China) Abstract: T he PS microspheres w ere prepared by dispersion polymerization of styrene in a mixture of ethanol and w ater, using AIBN and polyvinylpyrrolidone as the initiator and stabilizer, respec- tively. T he effects of the concentrations of the monomer, initiator and stabilizer, the reaction time and temperature, and the ratio of ethanol and w ater, on the long-range structural parameters such as molecular w eight w ere studied. It is show n that those experim