SAE-C2009P185-ICP鄄MS法测定陶瓷载体车用催化器中贵金属元素-中心.pdfVIP

摇 2009 中国汽车工程学会年会论文集 SAE鄄C2009P185 355 ICP鄄MS法测定陶瓷载体车用催化器中的贵金属元素 (1) (2) (1) (2) 刘悦 摇 方茂东 摇 李军 摇 李孟良 1郾 天津索克汽车试验有限公司摇 2郾 中国汽车技术研究中心 摇 摇 揖摘要铱摇 本文阐明了车用催化转化器中贵金属元素测定的重要性, 建立了电感耦合等离子体质谱法(ICP鄄MS)测定陶瓷载体样 品上Pt、 Pd、 Rh 三种贵金属元素的方法。 样品选择PtPdRh 三组分三效催化转化器, 用HCl+HNO +HF+HClO 的混酸加热的消解方 3 4 法, 采用ICP鄄MS法同时测定上述3种元素, 分析了干扰因素和质量控制方法, 确定了实验的最佳测定条件。 结果表明, 方法的精 密度不大于1郾1%, 加标回收率为98郾3% ~103郾8%。 该法已应用于车用催化转化器中贵金属元素含量及比例的测定。 摇 摇 揖关键词铱摇 催化转化器摇 贵金属元素摇 ICP鄄MS摇 Pt摇 Pd摇 Rh ICP鄄MS Measurement Method for PGM on the Ceramic Substrate of Vehicle鄄used Catalytic Converters 1 2 1 2 Liu Yue , Fang Maodong , Li Jun , Li Mengliang 1郾 Tianjin SwARCAutomotive Research Laboratory Co郾 , Ltd 2郾 ChinaAutomotive Technology Research Center 摇 摇 Abstract: This paper analyzed the importance of PGM measurement for vehicle鄄used catalytic converters, and set up the ICP鄄MS methodfor the Pt, Pd, Rh in the ceramic substrate vehicle鄄used catalytic converters郾 PtPdRh three鄄way鄄catalytic converter was chosen as thesample, andtheICP鄄MSmethodwasusedtomeasurethethreePGMafterthepretreatmentof samplebytheheatwithmixedacids of HCl, HNO , HF and HClO 郾 Also, the interferefactors and quality control methodswere analyzed andthe optimal measure condi鄄 3 4 tionwas set up郾 Astheresult showed, theprecision of method is small than 1郾1%, andtherecovery of standard addition is98郾3% ~ 103郾8%郾 This method is applied in the measurement of PGM loading and proportion of vehicle鄄used catalytic converters郾 摇 摇 Key