水泥改性铁矿石载氧体的煤化学链燃烧实验的研究.pdfVIP

第 33 卷 第 20 期 中 国 电 机 工 程 学 报 Vol.33 No.20 Jul. 15, 2013 40 2013 年 7 月 15 日 Proceedings of the CSEE ©2013 Chin.Soc.for Elec.Eng. 0258-8013 (2013) 20-0040-06 TQ 546 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 水泥改性铁矿石载氧体的煤化学链燃烧实验研究 陈定千，沈来宏，肖军，宋涛，顾海明，张思文 (能源热转换及其过程测控教育部重点实验室( 东南大学) ，江苏省 南京市 210096) Experiments on Chemical-looping Combustion of Coal With Cement-Decorated Iron Ore as Oxygen Carrier CHEN Dingqian, SHEN Laihong, XIAO Jun, SONG Tao, GU Haiming, ZHANG Siwen (Key Laboratory of Energy Thermal Conversion and Control of Ministry of Education (Southeast University), Nanjing 210096, Jiangsu Province, China) ABSTRACT: Experiments on chemical looping combustion of 载氧体的扫描电镜表征显示，水泥能够有效阻止载氧体颗粒 coal were conducted in a fluidized bed using cement- decorated 表面的晶粒在高温下的液相接触，降低载氧体颗粒氧化再生 iron ore as oxygen carrier. The reactivity of the oxygen carrier 过程中单位体积的热量释放强度，缓解烧结现象的发生，维 during redox experiments was investigated. The results indicate 持载氧体颗粒多孔的结构特性。 that the addition of cement effectively promotes the water-gas 关键词：化学链燃烧；铁矿石；载氧体；改性；水泥 shift reaction, leading to the decrease of CO fraction and the increase of H2 fraction in coal gasification products. After 0 引言 decorated the oxygen carrier gets its specific surface area and pore volume increased significantly, and reactivity improved as 化学链燃烧(chemical-looping combustion，CLC) a result. Further, the concentrations of CO and H in the flue 是一种新型燃料燃烧技术。它将传统的燃烧方式分 2 gas of the fuel reactor are far