关于储氢材料的毕业论文 LiBH4制备工艺的研究.docVIP

LiBH4制备工艺的研究 摘 要 本文LiBH4的制备工艺。在试验中，研究了LiBO2?8H2O的干燥工艺；分析了球磨LiBO2+Mg混合物反应的影响；同时还研究了温度和压力对球磨产物氢化时的影响。从结果中发现，LiBO2?8H2O最佳干燥工艺为：先在170 ℃时干燥2小时，然后在650 ℃下干燥3小时。LiBO2氢气气氛下球磨50LiBO2，同时还剩有部分未反应的Mg。℃氢化处理(氢气压力5 MPa)24小时后的产物比较复杂，但并不能得到LiBH4。但该球磨产物在250 ℃、7 MPa下氢化处理36小时后可以得到LiBH4。 Study on preparation process of LiBH4 Abstract LiBH4 was prepared successfully by Gas-Solid reaction of LiBO2+Mg+H2 in this work. The drying process of LiBO2?8H2O was investigated at first. The effects of ball milling on the reaction of the LiBO2+Mg mixture were then analyzed. Finally, the effects of hydrogenation pre