4-(2,4-二氟苯基)嘧啶辅助配体磷光材料合成解析.docVIP

4-（2，4-二氟苯基）嘧啶辅助配体磷光材料合成 XXX （XXXX） 摘要：近年来，高效有机电致磷光器件的研究和开发受到人们的极大关注重。金属配合物分子中能够产生强烈的自旋-轨道偶合，使原来禁阻的三重态跃迁变为允许，进而实现强的磷光发射，可以大大提高器件的发光效率。本文的研究目的是研制一种新型磷光电致发光材料，通过分子设计合成有机配体MDPP并合成(MDPP)2- Ir(Ⅲ)-Cl有机金属配合物氯桥联(其中，MDPP为5-甲基-2，3-二苯基吡嗪），以及首次合成4-（2，4-二氟苯基）嘧啶(DFPPM)辅助配体磷光材料，将其与(MDPP)2- Ir(Ⅲ)-Cl反应，并对其光学性能进行初步探究。再经过元素分析、红外、紫外及1H-NMR对其结构进行表征，证明该合成方法简单有效，反应速度快，产率高，引入杂质少，产品易于提纯。表征结果表明，实验合成的主配体MDPP以及首次合成的辅助配体4-（2，4-二氟苯基）嘧啶均达到较高纯度，合成得到的Ir(MDPP)2-(4-（2，4-二氟苯基）嘧啶)通过荧光光谱分析发现具有很好的磷光发射，为有机电致磷光器件提供很好的材料。 关键词：电致发光磷光材料ynthesis of 4 - (2,4- Difluorophenyl) pyrimidine phosphorescence materials. Chemical Processing Engineering of Forest Products，Beijing Forestry University,100083,P.R.China. In recent years, the research and development of efficient electroluminescent device phosphorescence have been much focused on. Metal complexes is able to generate strong spin-orbit coupling, resulting in prohibited triplet transitions into permitting, thereby achiev strong phosphorescence launch and it’s luminous efficiency can be greatly improved. The purpose of this study is to develop a new type of phosphorus Light-emitting materials. With molecular design, we synthesize MDPP and (MDPP)2- Ir(Ⅲ)-Cl Organic Complexes Metal chlorine Bridged (MDPP is stand for 5-methyl-2,3-diphenyl-pyrazine),and initially synthesize 4-(2,4-Difluorophenyl) pyrimidine (DFPPM) auxiliary ligand phosphorescence materials. And then make a reaction between DFPPM and (MDPP)2- Ir(Ⅲ)-Cl. Do a initial research into the optical properties of the product. After elemental analysis, IR, UV and 1H- NMR Characterization of the structure, it proves that the synthesis method is simple and effective, with many advantages such as high speed of reaction, high yield, low import of impurities,easy to products’ purification. The results indicate that MDPP and DFPPM have reached a higher purity. Through fluorescence spectroscopy, we can find that the product (MDPP)2- Ir(Ⅲ)-Cl -DFPPM has good phosphorescence launch, and provide good materials for elec