空气强化转炉钒渣湿法浸出行为.pdfVIP

第 65 卷 第 9 期 化 工 学 报 Vol.65 No.9 2014 年 9 月 CIESC Journal September 2014 空气强化转炉钒渣湿法浸出行为 刘作华，阿依努尔·努尔艾合买提，连欣，杜军，范兴，陶长元 （重庆大学化学化工学院，重庆 400044 ） 摘要：钒渣钠化焙烧过程低价钒氧化不充分，不能被浸出，降低了钒渣的浸出率。实验采用蒽醌磺酸钠（ADA ） 和栲胶作载氧体实现氧的传递，强化低价钒的氧化行为。通过 X 射线衍射、扫描电镜、紫外光谱以及紫外可见漫 反射光谱等检测方法，分析了转炉钒渣浸出反应前后物相变化行为，探索了反应过程机理，证实了其可行性。结 果表明，采用 ADA 和栲胶作载氧体，能将转炉钒渣中的低价钒氧化成可溶的高价钒，实现空气催化氧化高效浸 钒。此时，钒浸出率由 89.47%分别提高到 92.84%和 93.64%，且催化剂对体系后续工艺没有不良影响，转炉钒渣 中的尾渣含钒量由 1.1%分别降至 0.52%和 0.47% 。 关键词：浸取；催化；氧化 DOI ：10.3969/j.issn.0438-1157.2014.09.021 中图分类号：TF 803.21 文献标志码：A 文章编号：0438—1157 （2014 ）09—3464—06 Air strengthening of hydrometallurgy process for leaching vanadium from converter slag LIU Zuohua, Ayinuer·Nueraihemaiti, LIAN Xin, DU Jun, FAN Xing, TAO Changyuan （School of Chemistry Chemical Engineering, Chongqing University, Chongqing 400044, China ） Abstract: Low valency vanadium produced in the insufficient sodium roasting process affects the improvement of vanadium leaching rate. Anthraquinone-2,6-disulfonic acid disodium salt (ADA) or tannin as oxygen carrier was added into the water leaching process to transfer oxygen and to strengthen the air oxidation process of low valency vanadium. Phases of reaction system were analyzed using XRD, SEM, UV and UV-Vis DRS. The reaction mechanism of the process was also studied to prove its theoretical feasibility. Low valency vanadium was effectively oxidized by ADA or tannin, and vanadium leaching ratios increased from initial 89.47% to 92.84% and 93.64%, while vanadium contents in the leaching residue reduced from 1.1% to 0.52% and 0.47%, respectively. It