矿物之间的元素和同位素平衡_地质_省略_和等时线定年的热力学和动力学控制_郑永飞.pdfVIP

1000-0569/2011/027( 02)-0345-64 ActaPetrolog ica Sinica 岩石学报 : * 郑永飞 赵子福 ZHENG YongFei and ZHAO Z iFu , , 230026 CAS KeyLaboratory of Crust-MantleM aterials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, ef ei 230026, China 2010-10-10收稿, 2010-12-20改回1 Zheng YF and Zhao ZF1 20 111 E lem en t and isotope equ ilibrat ion b etw een m inera ls: Therm odynam ic and k inetic con trols of geotherm om etry and isochron dating1 A cta P etr olog ica S in ica 27 ( 2 ): 345 - 364 A bstrac t W ith respect to ineral S -Nd and Rb-Sr isochron dating of igneous and eta orphic rocks, a critical pre ise is that the chrono etric syste of ineral isochrones has achieved isotopic equilibriu during a given eta orphic event and the equilibriu has not changed afterwards1 An analogue to ineral chrono etry isO isotope geother o etry, so that this provides a utual constraint on validity of the wt o ethods1 Because the rates of S -Nd, Sr andO diffusion in igneous and eta orphic inerals are co parable under no inally anhydrous conditions, the state ofO isotope equilibriu between high-T inerals can provide a test for the validity of ineralS -Nd and Rb-Sr chrono eters1 Applicability of this principle is illustrated for ultrahigh-pressure eta orphic rocks fro the Dabie-Sulu orogenic belt in east-centralChina1 W hen ineralS -Nd isochrones do not always give consistentTriassic ages for eclog ite- facies eta orphis , ineralO isotope geother o etry do notyields concordant te peratures either1 There is a direct correspondence in equilibriu or disequilibriu statebetween the O andS -Nd isotopic syste sof eta orphic inerals1 So e o phacite-garnetpairs fro the eclogites exhibit O isotope equilibriu fractionations at ecl