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电沉积Fe-Co合金箔工艺及其微观结构的研究 应用化学专业　谢倩 指导老师　罗北平　教授 摘　要：本文采用电沉积方法制备铁钴合金箔，研究了电解液组成、电流密度、温度、pH值和稳定剂等因素对电沉积铁钴合金组成和沉积速率的影响，并得到电沉积铁钴合金箔的电解液组成及工艺参数：FeSO4 ·7H2O 40 g/L，CoSO4 ·7H2O 30 g/L， CoCl2 ·6H2O 10 g/L，硼酸 30 g/L，柠檬酸 40 g/L，抗坏血酸 10 g/L，糖精 1 g/L，十二烷基硫酸钠 0.1 g/L，电流密度为1~6 A/dm2、温度为30~70 ℃、pH值为0.5~2.5。 通过扫描电镜、能谱仪和x射线衍射仪对铁钴合金箔的微观形貌、组成和微观结构进行了分析，结果表明：铁钴合金箔具有良好外观和形貌。合金箔铁含量随电流密度的增加，先增后降；随着温度的增加，铁含量逐渐减小；而随pH值的增加，铁含量逐渐增大。含铁量不同，合金箔结构不同。随着电流密度、温度和pH值增加，镀层厚度先增大然后降低。 关键词：铁钴合金；箔；电沉积；工艺；微观结构 ABSTRACT：In the present paper, Fe-Co alloy foils were prepared by the method of electrodeposition. The influences of electrolyte composition, current density, temperature, pH value and stabilizer on the composition of the Fe-Co alloy foils and the deposition rate is discussed, and the electrolyte composition and process conditions of the electrodeposited Fe-Co alloy foils are obtained as follows: electrolyte composition: FeSO4 ?H2O,40 g/L, CoSO4 ?H2O 30 g/L, CoCl2 ?H2O 10 g/L, boric acid 30 g/L, citric acid 40 g/L, ascorbic acid 10 g/L, saccharin 1 g/L, sodium lauryl sulfate 0.1 g/L. process parameters: Current density = 1~6 A/dm2, temperature = 30~70 ℃, pH value = 0.5~2.5. The micro-morphology, microstructure and component of the Fe-Co alloy foils have been analyzed by scanning electron microscope, energy spectrometer and X-ray diffraction. The results show that the Fe-Co alloys has good surface topography; Fe-Co alloys foils exhibit different alloy phases as a function of their alloy composition. The foils thickness increase with the increasing of current density、temperature and the pH value, but the decrease was observed when current density increase higher. The content of Fe in the alloys foils increase with the increasing of current density, but the decrease was observed when current density increase higher. The content of Fe in the coatings keep increase with the increasing of the effects of pH and the content of Fe in the coatings keep decrease when temperature increase higher. Key word： Fe-Co