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编号 河南理工大学第期 “步步高”大学生科技攀登计划结项报告 水泥矿物固化氯离子的性能研究 立 项 人：所在单位：联系电话：参与学生：完成时间： 摘 要 氯离子是引起混凝土中钢筋锈蚀的重要原因，然而氯离子被固化后则可有效地延缓钢筋锈蚀。因此，研究氯离子在水泥基材料中的固化规律，对提高钢筋混凝土的使用寿命将有重要的意义。 为了研究水泥基材料固化氯离子的能力，本文首先选择合理的烧成制度制备纯水泥单矿（C3S、C2S与C3A），并采用XRD衍射仪对烧结物进行微观分析；其次，把制备的水泥单矿物掺入到水泥中，研究掺入一定量的单矿物后，不同水泥基材料在水化程度不同时它们固化氯离子的能力；最后研究在水泥中掺入不同的混合材粉煤灰和矿渣，研究它们固化氯离子的能力。实验结果表明：（1）在水泥单矿（C3A）烧成中，原料、烧成炉中垫板材料、压片时原料成型溶剂、压片的形状、压片的成型压力和温度制度等对单矿的烧成都有一定的影响；（2）在同等掺量的条件下，C3A固化氯离子的能力大于C3S固化氯离子的能力；（3）当溶液的PH值（本实验PH取12.5）固定时，单矿水化产物对氯离子的固化能力与溶液中氯离子的浓度值有很大关系。溶液中氯离子的浓度值越高，其固化能力越强；（4）当溶液为碱性且PH值（12.5）保持不变时，单位质量C4AH13、AFm和AFt晶体对氯离子的固化能力依次降低。 关键词：水泥基材料；水泥单矿；氯离子；固化  Abstract The Chloride ion is an important reason for corrosion of reinforced concrete, while it can delays the reinforcement corrosion effectively after the chloride ions are cured. As a result, it is necessary to study the chloride binding capacity of element-based, which will be of significance in improving the service life of concrete. The ability of cementatious materials curing chlorine ions, first choice reasonable burning schedule to prepare o study pure cement single mine(C3S、C2S and C3A), and conduct micro-analysis to sinter by XRD; and then put the pure cement single mine into the cement, research the ability of curing chlorine ions of different cementations materials in different degree of hydration with different cement single mine volume; last research the ability of curing chlorine ions with different fly ash and slag powder volume in cement. The results show that： (1) a single mine in the cement (C3A) firing, the raw material, firing furnace plate material, pressure films forming material solvent, tablet shape, tablet molding pressure and temperature of system-on-one Mine has a certain influence on firing; (2) the ability of curing chlorine ions of C3A is greater than C3S with content in the same conditions;(3) When the solution PH value (PH in this experiment taking 12.5) is fixed, single mineral hydration products of the curing ability