掺杂贵金属金的纳米二氧化钛纳米管的制备及其光催化性能研究精要.docVIP

掺杂贵金属金的纳米二氧化钛纳米管的制备及其光催化性能研究 摘 要 在实验室以将钛酸丁酯与丁醇为原料制备金红石相二氧化钛(TiO2)粉体, 并采用水热法将制备金红石相二氧化钛(TiO2)粉体合成二氧化钛纳米管(TNTs)，在酸性条件下将HAuCl4溶液与柠檬酸三钠溶液添加到含金红石相二氧化钛(TiO2)粉体的巯基乙酸溶液反应，得到表面载Au的二氧化钛纳米管(Au/TNTs)。之后利用透射电镜(TEM)、X 射线衍射(XRD)对产物进行了表征。对制得的掺金二氧化钛纳米管的光催化性能的探究，主要是Au/TNTs对甲基橙(MO)紫外光催化降解性能。结果表明，经Au 表面修饰后，二氧化钛纳米管的晶型结构没有发生明显变化，并且Au 粒子能很好地分散在纳米管的外表面.。Au粒子的直径约为4 nm，以单质Au的形态存在.。经过可见分光光度计测试后发现Au/TNTs在可见光区域表现出较强的吸收，光催化降解甲基橙实验结果表明，Au/TNTs 的光催化活性较金红石相二氧化钛粉体和纯TNTs有着显著的提高。 关键词： 金属金 二氧化钛 纳米管 光催化 ABSTRACT Titania nanotubes (TNTs) were synthesized by hydrothermal treatment of rutile phase TiO2 nanoparticlesin 10 mol·L-1NaOHsolution at 110℃for 24 h. The Au loaded titania nanotubes (Ag/TNTs) were obtained by chemicaldeposition method with the TNTs suspending .The characterizations of the as synthesized samples were performed by TEM, XRD, and spectra. The photocatalytic performance of the Au/TNTs was investigated by UV light induced photocatalytic decomposition of methyl orange(MO). The results showed the shape and the crystalline of the nanotubes were not changed after the modification. The zerooxidation state Au quantumdots, about 4 nmin diameter, were well dispersed on the external surface of the nanotubes.Au/TNTs exhibited enhanced absorption at the visible range in the UV-Vis spectra. The Au nanoparticles were foundto significantly enhance the photocatalytic activity of TiO2 nanotubes, and the catalyst system was demonstrated to behighly efficient for the UV light induced photocatalytic decomposition of MO compared to both rutile phase TiO2nanoparticles and pure TNTs. After irradiation for 60 min, the decomposition rates of MO solution in rutile phase TiO2nanoparticles, TNTs, and Au/TNTs systemwere significantly improvement. KeyWords： Nanotubes; Titania; Au ; Photocatalysis 目 录 一 前言 …………………………………………………………………………1 1.1二氧化钛纳米材料的介绍……………………………………………………1 1.2二氧化钛纳米材料在环境净化上的应用……………………………………1 1.3二氧化钛纳米材料的改性……………………………………………………2 1.4掺杂贵金属的二氧化钛纳米管的研究进展…………………………………3 1.5实验设计思路……………………………