纯流体热力学性质(PartB)解读.pptVIP

The saturated pressure of 1-butene liquid at 273.15K is determined by the following method: For normal point, Tn=267 K, psat=1.0133 bar; for critical point, Tc=419.6 K, pc=40.2 bar. Therefore we can obtain the solution of A and B as A = 10.126 B = 2699.11 Then we calculate the saturated pressure of 1-butene liquid at 273.15 K as psat=1.2771 bar. (p1=1.27 bar) Step 1: Vaporization of saturated 1-butene liquid at 273.15K △H lv is the latent heat of vaporization(蒸发潜热). The latent heat of vaporization at normal point is calculated by the following Riedel equation Wi