淀粉CNs高吸水树脂对重金属离子的吸附性能研究详解.docVIP

本科毕业论文 淀粉接枝AA/AM/CNWs高吸水性树脂的合成及应用研究 2013年6月 本科毕业论文 淀粉接枝AA/AM/CNWs高吸水性树脂的合成及应用研究 摘 要 淀粉接枝高吸水树脂是一种新型的功能高分子材料，可广泛应用于石油工业、农业、医疗卫生等各个领域。本文以过硫酸铵为引发剂N,N-亚甲基双丙烯酰胺为交联剂，采用溶液聚合法合成了淀粉接枝丙烯酸、丙烯酰胺类高吸水性树脂，并研究了单体比、PH值等因素对接枝产物吸水性能的影响，比较了树脂吸蒸馏水和盐水情况。 本文以过硫酸钾为引发剂，以N,N -亚甲基双丙烯酰胺为交联剂,将淀粉与丙烯酰胺、丙烯酸、纳米纤维素晶须在水溶液中聚合制备高吸水性树脂。本文以可溶性淀粉、AA、AM为聚合单体，CNWs为填充物，过硫酸铵作引发剂，N,N-亚甲基双丙烯酰(NMBA)胺作交联剂，采用水溶液聚合法，合成了一种无毒、无害的新型高吸水树脂。并考察了单体配比、pH值、引发剂及交联剂的用量对淀粉/AA/AM/CNWs高吸水树脂吸水性能的影响，确定了聚合反应最佳合成工艺条件为：m(AA):m(AM)为3:1；单体与淀粉的质量比为9：1Abstract Cassava starch grafted Super-absorbent resin is a kind of new functional Polymer materials, which are widely used in various fields such as Petroleum industry, agrleulture,medicine and hygiene. In the paper, With the potassium persulfate as the initiator and N,N,-the-methyl radical double acrylic amide as the crosslinking agent,the starch-grafted polyacrylate high water-absorbent resin was synthesized by solution polymerization method. In the picture,a kind of high - performance water - absorbent resin had been successfully synthesized by a simple method using potassium peculated as initiator, N,N’- Methylenebisacrylamide as cross linker, and starch , acrylamide and acrylic acid and cellulose nanowhiskers as raw materials reaction in aqueous solution. The effects of comonomer ratio, pH, amount of initiator and cross-linking agent are studied to the absorption of starch/AA/AM/CNWs superabsorbent resin and the optimum conditions are determined. The best synthetic conditions as follows: the mass ratio of AA and AM is 2:1, the mass ratio of comonomer and starch is 9:1, the value of pH is 5, the mass percentage of initiated is 1.0%, the weight of crosslinking is 0.4 %. Under these conditions, this superabsorbent polymer is capable of absorbing distilled water up to 416 g/g and 0.9 wt% NaCl solution 75 g/g. The resin was characterized by FTIR and SEM spectrophotometer. Keywords: Superabsorbent resin; acrylic acid; cellulose nanowhiskers ; acrylamide; starch; 目