中心金属原子对萘酞菁化合物激发态的光学非线性增强效应.pdfVIP

第44 卷第2 期 红外与激光工程 2015 年2 月 Vol.44 No.2 Infrared and Laser Engineering Feb.2015 Central metal ion enhances the excited state optical nonlinearity of naphthalocyanine compound Chang Qing, Chang Cun, Kong Degui, Gao Yachen, Gao Meiling (College of Electronic Engineering , Heilongji ang University , Harbin 150080 , China) Abstract: The third order optical nonlinearities of lead and palladium naphthalocyanine compounds were studied comparatively using Z -scan technique with ns laser pulses at 532 nm. The experimental results showed that the two kinds of naphthalocyanine compounds also indicated strong nonlinear absorption (reserve saturable absorption) and nonlinear refraction (self focusing) characteristics . Nonlinear absorption coefficient for lead and palladium naphthalocyanine compounds by theroetical fitting were 6.54伊10-10 m/W and 3.90 伊10 -10 m/W , reprectively . Nonlinear refractive index coefficient n2 were 1.68 伊 10 -10 esu and 8 .04 伊 10 -11 esu, reprectively . The second order molecular hyperpolarizabilities were 3.44伊10-28 esu and 2.57 伊10 -28 esu, reprectively , which were approximately about 105 order in magnitude than that of CS2 (4.32 伊10 -33 esu) . The experimental results show that the lead naphthalocyanine compound exhibits great optical nonlinearities than palladium naphthalocyanine compound results from the heavy metal atoms as central atom of naphthalocyanine lead compounds enhance the optical nonlinearities of naphthalocyanine compounds. Key words: third order op