不同前处理方法检测食品中重金属含量.pdfVIP

现代食品科技 Modern Food Science and Technology 2008, Vol.24, No.10 不同前处理方法检测食品中的重金属含量 杨雪娇 1 1 1 2 1 ，黄伟 ，林涛 ，余以刚 ，赵建恩 (1.东莞出入境检验检疫局，广东 东莞 523072)（2.华南理工大学轻工与食品学院，广东 广州 510640) 摘要：采用高压密闭微波消解、干法灰化、湿法消解以测定食品样品中的铅、砷、汞。结果表明，微波消解测定标准样品的变 异系数小，准确度高，空白值低，对三种元素的回收率皆较高，且所需的时间也较短。干法消解可用于称样量大的样品，但准确度较 低，空白值高，回收率偏低，对于易挥发的元素和含无机盐成分高的食品不适用。湿法消解可同时消化多个样品，但准确度较低，空 白值较高，回收率较低，试剂消耗量大，能量消耗大。 关键词：铅；砷；汞；微波消解；湿发消解；干法消解 中图分类号：TS201.6；文献标识码：A ；文章篇号:1673-9078(2008)10-1051-05 Determination of Heavy Metal Contents in Foodstuffs by Three Pretreatment Methods 1 1 1 1 YANG Xue-jiao , HUANG Wei , LIN TAO , YU Yi-gang, ZHAO Jian-en （1.Dongguan Entry-exit Inspection and Quarantine Bureau , Dongguan 523072, China ）（2. College of Light Industry and Food Sciences , South China University of Technology, Guangzhou 510640, China ） Abstract: Three methods, microwave, dry and wet digestion, were used for the decomposition of the foodstuffs and then the content of Pb, As, Hg in the pretreated foodstuffs were determined. Results showed that the smallest variation coefficient, shortest test time and highest veracity were achieved with microwave digestion, while the blank value was somewhat low. Dry digestion method was suitable for treatment of the sample with large quality but foods containing non-volatile elements or high abio-salt. However, it suffered from lower precise and recovery rate and the largest blank value. The wet digestion method can be used for treatment of several samples together, but had some weak points, such as larger blank value, lower recovery rate, and larger consumption of reagent and energy. Key words: Pb; As; Hg; microwave digestion; wet