不同载体成型的MoZSM-5催化剂上甲烷无氧芳构化反应.pdfVIP

2010 Chinese Journal of Catalysis Vol. 31 No. 3 文章编号: 0253-9837(2010)03-0348-05 DOI : 10.3724/SP.J.1088.2010.90939 研究论文: 348~352 不同载体成型的 Mo/ZSM-5 催化剂上甲烷无氧芳构化反应 1,2 1 1 1 任冬梅 , 王祥生 , 李 钢 , 刘海鸥 1 大连理工大学催化化学与工程系精细化工国家重点实验室, 辽宁大连 116012 2 渤海大学化学化工学院, 辽宁锦州 121000 摘要：以不同氧化物为载体, 通过挤条成型法制备了 Mo/ZSM-5 催化剂, 考察了其催化甲烷无氧芳构化反应性能. 采用吸附吡啶 红外光谱、氨程序升温脱附和氢程序升温还原等方法对催化剂进行了表征. 结果表明, ZnO 的添加使催化剂的强酸量减少, 强 B 酸比例降低, Mo 物种还原能力提高, 因而催化剂表现出较高的甲烷芳构化活性和较低的积炭选择性. 关键词：钼; ZSM-5 分子筛; 挤条成型催化剂; 甲烷; 芳构化 中图分类号：O643 文献标识码：A Methane Dehydroaromatization in the Absence of Oxygen over Mo/ZSM-5 Extruded with Different Oxides 1,2 1,* 1 1 REN Dongmei , WANG Xiangsheng , LI Gang , LIU Hai’ou 1State Key Laboratory of Fine Chemicals, Department of Catalytical Chemistry and Engineering, Dalian University of Technology, Dalian 116012, Liaoning, China 2Faculty of Chemistry and Chemical Engineering, Bohai University, Jinzhou 121000, Liaoning, China Abstract: The Mo/ZSM-5 catalysts extruded with various oxides as supports were prepared. Fourier transform infrared spectroscopy of pyridine adsorption, NH temperature-programmed desorption, and H temperature-programmed reduction were employed to characterize