锌铝水滑石负载羧酸基酞菁锌可见光降解水中氯苯酚.pdfVIP

第 32 卷第 11期 环　 境　 科　 学　 学　 报 Vol.32,No.11 2012年11月 　Acta Scientiae Circumstantiae Nov. ,2012 蔡苏彦,孙琼,许宜铭.2012.锌铝水滑石负载羧酸基酞菁锌可见光降解水中氯苯酚[J].环境科学学报,32(11):2725-2731 Cai S Y,Sun Q,Xu Y M. 2012.Immobilization of zinc phthalocyaninecarboxylate onto Zn/ Al-hydrotalcites for chlorophenol degradation in water under visible light [J].Acta Scientiae Circumstantiae,32(11):2725-2731 锌铝水滑石负载羧酸基酞菁锌可见光降解水中氯苯酚 蔡苏彦,孙琼,许宜铭∗ 浙江大学化学系,杭州310027 收稿日期:2012-01-10　 　 　 修回日期:2012-02-11　 　 　 录用日期:2012-03-01 摘要:以锌铝类水滑石为载体,1.0%(质量分数)水溶性羧酸基酞菁锌为光敏剂,制备了不溶于水的负载型光敏剂,并对其结构进行表征.结果 表明,在可见光和氧气作用下,该复合催化剂能够引发水中对氯苯酚、2,4-二氯苯酚和2,4,6-三氯苯酚的降解.但有机物降解的速率与载体的 锌铝比和煅烧温度有关.研究表明,最佳的锌铝比和煅烧温度分别为2.0 和300 ℃.在反应过程中,载体及其煅烧产物具有电子导体的功能,可 加快光敏剂与氧气之间的电子转移过程,进而引发氯苯酚的降解.此外,该复合催化剂能被重复循环使用,但光敏活性逐渐降低. 关键词:酞菁锌;水滑石;氯苯酚;可见光;降解 文章编号:0253-2468(2012)11-2725-07　 　 　 中图分类号:X703　 　 　 文献标识码:A Immobilization of zinc phthalocyaninecarboxylate onto Zn/ Al-hydrotalcites for chlorophenol degradation in water under visible light CAI Suyan,SUN Qiong,XU Yiming∗ Department of Chemistry,Zhejiang University,Hangzhou310027 Received 10 January2012;　 　 　 received in revised form 11February2012;　 　 　 accepted 1March2012 Abstract:Layered double hydroxides (LDH) with different Zn/ Al atomicratioswereused asa support of water solublezinctetracarboxylphthalocyanine (ZnPc) at 1.0%. In the presence of visible light and O ,this immobilized sensitizer wasvery activefor the degradation of4-chloro-,2,4-dichloro- and 2 2,4,6-trichlorophenol in water at pH6.5,whereas in the presence of LDH or ZnPc,organic degradation was absent or very slow. However,the rate of organic degradation wasinfluencedbytheZn/ Alratioandsinteringtemperatureof LDH. TheoptimumZn/ Alratiowas2.0 andsinteringtemperaturewas 300 ℃. ItisproposedthatbothLDHanditsthermallydecomposedproductsa