乙烯基乙酸酯合成钯-金催化剂中金助催化作用.pdfVIP

29 11 2008 11 Vol. 29 No. 11 Chinese Jour nal of Catalysis N ovember 2008 : ( 200 8) : 1178~ 1186 1 2 陈明树, D. W. GOODM AN ( 1 厦门大学化学化工学院化学系和固体表面物理化学国家重点实验室, 福建厦门36 1005 ; 2 德克萨斯A M 大学化学系, 德克萨斯 科利奇站, T X 7784230 12 , 美国) : ( V A) , , X . , , , / , VA . , , , . : ; ; ; ; : O643 : A Promotional Effects of Au in PdAu Catalysts for Vinyl Acetate Synthesis 1 2* CHEN Mingshu , D. W. GOODMAN (1 State K ey L aboratory of Physical Chemistry of Solid Surf aces, D ep artment of Chemistry , College of Chemistry and Chemical Engineer ing, X iamen Uni ersity , X iamen 361005 , Fuj ian, China; 2 Dep artment of Chemistry , Texas A M Uni ersity , College S tation, TX 778423012 , USA ) Abstract: S l ca supported PdAu b metall c catalysts ar e h g hly select ve for the acetox ylat o n of ethylene to v nyl acetate ( VA) . In t h s study w e have u sed model catalysts cons st ng of planer surf aces and supported nanopart cles to nvest g ate the promot onal eff ects of Au n PdA u b metall c catalysts. L ow energ y on scatter ng spectroscopy, low ener gy electron d ffract on, Xray photoelectron spectroscopy, nfrared reflect on adsorpt o n spectroscopy, and temperatureprogram