化工学院毕业设计(优秀)环氧树脂阻燃剂的合成及表征.docVIP

北京理工大学 毕业论文 环氧树脂阻燃剂的合成及表征 学 院: 化工与材料学院 专 业： 姓 名： 指导老师： 化学工程与工艺 学 号： 职 称： 教授 中国 二○一五 年 五 月 北京理工大学毕业论文 诚信承诺书 本人郑重承诺：我所呈交的毕业论文《环氧树脂阻燃剂的合成及表征》是在指导教师的指导下，独立开展研究取得的成果，文中引用他人的观点和材料，均在文后按顺序列出其参考文献，论文使用的数据真实可靠。 承诺人签名： 日期： 年 月 日 环氧树脂阻燃剂的合成及表征 摘 要 DOPO（9，10-2氢-9-氧-10磷杂菲-10-氧化物）和4HBA（4-羟基苯甲醛）通过加成反应合成DOPO-HB(2-6-氧-6-氢-二苯并磷氧杂-6-酮4-羟基苯甲醇Synthesis and Characterization of Epoxy Resin Flame Retardant Abstract A novel phosphorus-containing hydroxyl benzoaldehyde (DOPO-HB) from 9,10-dihydro-9-oxa-10– phosphaphenanthrene -10-oxide (DOPO) and 4-hydroxyl benzoaldehyde was obtained via simple addition reactions.The synthesis conditions of DOPO-HB were also optimized A novel phosphorous -containing flame retardants 10-(2,5-dicarbonylpropyl) 9,10-dihydro-9-oxa-10-phospha- phenanthrene-10- oxide (DOPO-ITA) was synthesized using 9,10-dihydro-9-oxa-10-phospha-phenanthrene-10-oxide (DOPO) and itaconic acid(ITA) as starting materials.The chemical structure of the obtained DOPO-HB and DOPO-ITA were characterized with FTIR, 1H and 31P NMR and elemental analysis. The DOPO-HB, with multi-phenol groups in the molecular chain, was used as a poly functional curing agent for epoxies. The activity and activation energies of the DOPO-HB curing reactions with epoxies were investigated with differential scanning calorimetry (DSC). The thermal properties and thermal degradation behaviors of the DOPO-HB-cured epoxy resins were also studied with DSC and thermo gravimetric analysis(TGA). The paper also focuses on the solubility of DOPO-HB in different solvents with the temperature trend, the results show that, the solubility of DOPO-HB in benzene, toluene and xylene, and water increases with the temperature rising. Moreover, the benzene xylene toluene Water Keywords: Epoxy resin Curing agent Flame retardant solubility 目 录 摘 要 I Abstrac