DSC-TG-STA原理与应用详解.ppt

The TG curve comparison shows the influence of the CO2 atmosphere on the decomposition of dolomite very drastically: the decomposition reaction produces CO2, therefore external CO2 atmosphere delays the decomposition by more than 100 °C. Interesting is also that the second decomposition step, the decomposition of the calcium carbonate, is much more influenced by CO2 than the first step, the decomposition of the magnesium carbonate. This is confirmed also in literature. Similar effect can be achieved, when higher partial pressure of CO2 is created by the sample itself (higher quantity, structur