09 化学修饰电极讲解.ppt

* * * * 由于它们几乎不溶于任何溶剂，直接制备其薄膜修饰电极十分困难。?? 通过适当的手段将它们分散在适当的溶剂中. 分散法： 超声分散（单一溶剂或有特效分散试剂存在下）＋挥发成膜 将SWNT分散在二甲基甲酰胺(DMF)中(Anal. Chem. 2001, 73:915-920) 详细地研究了SWNT修饰电极的特性（SEM，XPS，Electrochemical） 对DA，AA，及EP有电催化活性； 碳纳米管-Nafion分散体系 制备的MWNT－Nafion复合膜修饰电极不仅具有碳纳米管的特性，而且还兼有Nafion膜的离子选择渗透性能。 利用DA、AA和UA等在同一介质中存在形式的不同（主要是所带电荷不同），实现了DA的高选择性和高灵敏分析。 《高等学校化学学报》, 23(2002) 2067-2069 J. AM. CHEM. SOC. 2003, 125, 2408-2409 碳纳米管-DHP分散体系 此复合膜均匀、稳定、使用寿命长，重现性好，已确定广泛的应用。 A B SEM images of DHP film (A) and MWNT-DHP film (B) on GCE surface Analytical Biochemistry (2003) 318(1) 100-106. Simultaneous determination of dopamine and serotonin Nanotechnology 15 (2004) 287–291 application to determining thyroxine simultaneous determination of cadmium and lead Analytica Chimica Acta_489(02)215-221_2003 Direct electrochemistry of DNA Analytical and Bioanalytical Chemistry 376:205-209_2003 Low Potential Amperometric Determination of Ascorbic Acid Bulletin of the Korean Chemical Society_26(09)1403-1409_2005 (a) Procedure of assembling enzymes on a carbon nanotube (CNT) by layer-by-layer (LBL) technique. (b) 3-D image of PDDA/enzyme/PDDA/CNT nanocomposite. Enzyme-CNT biosensors J. Nanosci. Nanotechnol. 6 (2006) 948. (a) Procedure of assembling enzymes on a carbon nanotube (CNT) by layer-by-layer (LBL) technique. (b) 3-D image of PDDA/enzyme/PDDA/CNT nanocomposite. Enzyme-CNT biosensors J. Nanosci. Nanotechnol. 6 (2006) 948. DNA/CNT biosensors Wiring of proteins by graphene for electrochemistry. Graphene-oxide (GO)-supported heme proteins at the surface of glassy-carbon electrodes (for convenience, oxygenated functional groups at the surface of GO are not shown Electrochemical biosensors (A) FESEM images of graphene nanosheets were taken from two different directions (left, cross view; right, lateral view). (B) DPVs of GC (a and b) and GNSs/GC (c and d) in the absence (a and c) and presence (b and d) of 20.0 M of morphine (M), noscapine (N) and heroin (H). Graphene nanosheets modified glassy carbon elect