聚多巴胺亲水改性锂硫电池分析.pptVIP

文献汇报 Disadvantage hydrophobic surface, which seriously hinder the adequate uptake and diffusion of organic electrolytes within the separators. Moreover, it is difficult to completely ensure the electrical isolation between the cathode and anode due to their poor thermal shrinkage, leading to low capacity, poor power capability and security risks upon cycling. Polydopamine Polydopamine, with a molecular structure that incorporates many functional groups such as catechol, amine and imine, can be easily deposited on all types of inorganic and organic substrates, even super-hydrophobic surfaces. Experimental S:AB=6:4 300r/h球磨 2h put it into a PTFE container filled with argon container was heated at 155 °C for 12 h cooled down to room temperature S/C composite :acetylene black:PTFE=7:2:1with ethanol as a dispersant compressed into a thin piec cut into a disk film of 8mm in diameter and 1.5~1.8 mg in weight dried in the oven at 55 °C for 12 h The surface modification of separators separators were soaked into 50 ml methanol solution (30 minutes) put into the dopamine solution(24h) rinsed with distilled water for several times dried at 30 °C for 12 h. Results It can be observed from Fig. 1 that the weight loss of the composite begin from about 150 °C, and finished over 400 °C, due to evaporation of sulfur from the meso/micropores of the host carbon. It is shown that the carbon black appears as a loose particle aggregated of some uniform and small carbon spheres. For the S/C composite with 60 wt% sulfur loading, the aggregates become denser and the partical size become bigger as compared to the carbon black. Results wetting test after dropping an organic electrolyte [1 wt% LiNO3 and 1.0 M 30 LiN(CF3SO2)2 dissolved in DOL/TEGDME, v/v= 1:1)] onto the surface of the separator, the droplet can hardly wet the bare separator (left), whereas the PDA modified separato (right) is fully wetted immediately. Results It can be seen