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17 Study of the Temperature Influence on Concrete Hydration Exothermic Rate
Study of the Temperature Influence on Concrete Hydration Exothermic Rate
Abstract: Recent achievements about concrete hydration exothermic models based on Arrhenius equation have improved computation accuracy for mass concrete temperature field. But property of activation energy and gas constant (Ea/R) has not been well studied yet. From latest experiments it is shown that Ea/R obviously changes with the hydration degree without fixed form. In this paper, the relationship between hydration degree and Ea/R is studied and a new hydration exothermic model is proposed to use it and testify it. With those achievements, mass concrete temperature field with arbitrary boundary condition can be calculated more precisely.
Key words: hydration exothermic model, Arrhenius equation, activation energy, hydration degree, temperature rise model.
1 Introduction
Thermal crack is one of the most common cracks of concrete [1, 2]. Hydration exothermic behavior of the concrete should be taken into consideration when calculating mass concrete temperature field [3, 4]. Adiabatic temperature rise can be measured by concrete adiabatic temperature measuring device or back analyzed by the data of field experiment [5, 6]. Adiabatic temperature rise got by concrete adiabatic temperature measuring device is more accurate and less expensive than back analysis from field experiment. However, hydration exothermic rate of the concrete is influenced by concrete temperature duration which should be taken into consideration [7-10].
There have been several concrete adiabatic temperature rise models to solve this problem and several of them are based on Arrhenius equation [11-14]. However there are some common problems:
(1) For those models, the ratio between the activation energy and the gas constant is reduced to a constant or simply considered as a fixed function type. Laboratory tests in this paper showed that those reductions are not proper for all kinds of concrete.
(2) For those models, adiabatic
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