30万吨每年直馏柴油醇氨法化学精制装置工艺设计说明书解说.doc

30万吨/年直馏柴油醇氨法化学精制装置工艺设计 摘要 国内外炼油和化工企业一直采用碱洗-电精制-硫酸中和法进行精制直馏柴油和回收副产品环烷酸，虽然柴油产品能够合格，但是该工艺上仍然存在着柴油收率较低、乳化严重、间歇操作、操作费用较高和环境污染等问题。人们一直在努力开发新型的、高效的精制直馏柴油和回收副产品环烷酸的联合工艺。 醇氨法精制直馏柴油的工艺存在着选择破乳剂困难、精制柴油中残余溶剂含量高、溶剂的循环量较大，需要全部再生或者部分再生，以及再生能耗高等技术经济问题。为了解决这些问题，采用静态混合器和溶剂循环再生，对醇氨法精制直馏柴油工艺进行优化设计。本项目醇氨法采用氨-乙二醇体系作溶剂, 具有不使用高压电场、不使用强酸强碱、没有“三废” 排放、溶剂能循环使用、连续操作，且同时得到精制柴油和环烷酸等优点。 关键词：直馏柴油；环烷酸；醇氨法精制；乙二醇 The Process Design of 30Mt/a Alcohol-ammonia Chemical Extraction for Refining Straight-run Diesel Abstract Oil refining and chemical enterprises at home and abroad have been using alkaline cleaning - electrofining sulfuric acid neutralization to refined straight-run diesel and recycling byproduct naphthenic acid, although diesel products can be qualified, but the process still exist on the diesel yield is low, serious emulsification, intermittent operation, high operation cost and environmental pollution problems. People have been refined to the development of new, efficient straight run diesel and recovery of by-product naphthenic acid combined process. Refined straight-run diesel by alcohol ammonia refining process there are choosing demulsifier difficulties, high residual solvent content in the refined diesel oil, the circulation of the solvent amount is larger, need all or part of regenerative, and high energy consumption of regeneration technology economic problems. In order to solve these problems, the use of static mixer and solvent recycling, refined straight-run diesel by alcohol ammonia process optimization design. The project of alcohol ammonia method adopts ammonia - system of ethylene glycol as solvent, has not use high voltage electric field, do not use strong acid alkali, no three wastes emissions, solvent can be recycled, continuous operation, and at the same time get the refined diesel and naphthenic acid, etc. Keyword: straight-run diesel；naphthenic acid；Alcohol ammonia?refining；ethylene glycol  目录 前言 1 第一章 绪论 2 1.1 项目概览 2 1.2 设计依据 2 1.3 项目背景 2 1.4 产品及原料方案 3 第二章 工艺流程设计 4