热塑性弹性体SBS介绍.docVIP

热塑性弹性体SBS介绍 中国石化北京北化院燕山分院自主开发的3万吨/年SBS工业生产技术，其工艺是由丁二烯和苯乙烯通过烷基锂引发剂在有机溶剂中经嵌段共聚而成。 在工艺开发方面，将聚合釜体积由30M3扩大到54M3，采用夹套和内冷管同时撤热，搅拌为上置式四层CBY型复合悬臂桨，使聚合釜单釜生产能力达到1.5万吨/年；采用绝热闪蒸，充分利用约100℃聚合胶液的显热，通过闪蒸出一部分溶剂降低了溶剂回收单元的负荷；通过改进凝聚釜内搅拌及蒸汽分布，将60 M3凝聚釜扩大为100 M3，并采用双釜逆向串联凝聚工艺，提高了单线生产能力和凝聚效果；溶剂回收采用脱水脱重为一塔的溶剂精制流程并由常压精馏改为带压精馏，降低了能耗和物耗；在聚合物后处理单元采用挤压脱水、带式干燥技术及抗产品粘结技术，提高了装置的生产能力；采用吸收式热泵（AHT）技术回收凝聚釜顶汽提气40%的低温余热等措施，使整体能耗物耗得到大幅度降低，每吨SBS干胶消耗丁二烯和苯乙烯1015kg，溶剂35kg，蒸汽5.0吨，引发剂3.0kg，循环水250吨，电500kwh。 在品种牌号开发方面，为满足不同客户的需求，进行了目标市场的细分，在原有线型、星型及充油型牌号基础上开发出适应不同应用领域的众多专用牌号。应用领域包括沥青改性、胶粘剂、制鞋、聚合物改性等。 牌号 SBS1301 SBS1401 SBS4303 SBS4402 SBS4452 苯乙烯/丁二烯 3/7 4/6 3/7 4/6 4/6 密度 0.94 0.95 0.94 0.95 0.94 填充油(phr) 50 扯断强度 (Mpa) 24 28 18 26 17 300%定伸强度 (Mpa) 2.2 4.0 3.0 5.0 1.4 断裂伸长率(%) 900 750 700 750 1000 邵氏硬度A 70 93 80 90 69 主要用途 沥青改性 粘合剂 沥青改性 制鞋 制鞋 Yansan Branch of Sinopec Beijing Research Institute of Chemical Industry has independently developed by itself a commercial production technology of SBS with a capacity of 30, 000 tons/year. The technology involves batchwise copolymerization of butadiene and styrene initiated by alkyl-lithium in an organic solvent, in which the block copolymer (SBS) forms. In the aspect of process development, the volume of the polymerization reactor is expanded from 30 M3 to 54 M3. Jacket and inner cooling tube are adopted simultaneously to remove reaction heat. The stirring apparatus takes a configuration of upper four-layer CBY complex cantilever paddle, so that the production capacity of a single reactor reaches 15, 000 tons/year. A technology of adiabatic flashing is used to make full use of the sensible heat from the rubber cement at 100℃ during flashing process. The load of solvent recovery unit is lowered by flashing a part of the solvent. The condensation kettle is expanded from 60 M3 to 100 M3 by improving the stirring and steam distribution in the condensation kettle. The production capacity and condensation effectiveness of a single line is raised by adopting a c