表面活性剂在低渗透油藏中的应用毕业论文.doc

表面活性剂在低渗透油藏中的应用 摘 要 针对我国低渗透油田采收率较低、开发效果的况，本文对在没有碱性条件下、能与中原油田文 92 北块原油，产生超低界面张力的几种阴离子－非离子表面活性剂驱油剂体系进行了室内研究，最终确定出了适合文92北块的表面活性剂驱油体系。首先考察了这 7 种体系的界面张力和配伍性能，进行配方筛选，并对性能较好的三种体系 SHPC3、SHPC4 和 SHPC7 进行了浓度优化，确定最佳使用浓度为 0.28%。然后对这三种表面活性剂进行耐温、吸附性、抗盐性、乳化性、稳定性等性能进行评价，筛选出了一种乳化能力较强、静态咐附量较低、耐高温抗盐的表面活性剂驱油体系 SHPC7，可达超低界面张力（10mN/m）、耐温能力 96℃，抗盐能力达15.24×10mg/L，抗钙镁能力达 5763mg/L。 然后通过室内人造低渗透非均质岩心物理模拟驱油实验评价了SHPC7 驱油体系对提高采收率的影响，发现在注入浓度相同、注入时机相同（均为 0.28%）时，注入量增大，采收率增大，注入 0.4PV 的 SHPC7 段塞采收率增值最大，比水驱采收率高 5.68%；注入 0.2PV 的 SHPC7 段塞较注入 0.1PV 的相应段塞增值提高了 1.34%，而注入0.3PV 的SHPC7 段塞较注入 0.2PV 的相应段塞采收率增值提高了 0.21%。 因此，优选文92-31 井组进行表面活性剂驱施工方案设计，采用注入 0.4PV 的SHPC7 表面活性剂体系，不仅降低成本，又能达到提高采收率的目的。 关键词：表面活性剂；低渗透油藏；界面张力；耐温抗盐；乳化性； Abstract According to the conditions of low waterflooding recovery efficiency of low permeability reservoirs in Zhongyuan Oilfield, in order to screen surfactant flooding system available to W92 northern reservoir, experiments of seven Nonionic-Anionic surfactant flooding systems which could lead to ultra-low interfacial tension with the oil of W92 northern reservoir were carried out in the lab without alkali. In this paper, we have examined interfacial tension and compatibility of seven surfactant flooding systems to screen the best formula, and optimized the concentration of three Surfactant Flooding Systems (SHPC3, SHPC4 and SHPC7) with superior performance. The best concentration of these three systems is 0.28%. Then through performance evaluation of resistance to temperature and salinity, adsorptivity, emulsitify and stability, SHPC7 with better emulsification, resistance to temperature and salinity and ultra-low interfacial tension was selected, whose limitation to temperature, salinity, and Ca Mg is 96℃, 15.24×10mg/L and 5763mg/L respectively. Then theeffectiveness for EOR of coreflooding experiments using SHPC7 surfactant flooding system whose concentration is 0.3% was investigated with low permeability heterogeneity artificial cores. Experiments showed that under the