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Entropy (YAC- Ch. 6) Introduce the thermodynamic property called Entropy (S) Entropy is defined using the Clausius inequality Introduce the Increase of Entropy Principle which states that the entropy for an isolated system (or a system plus its surroundings) is always increases or, at best, remains the same. Second Law in terms of Entropy Learn to use the Entropy balance equation: entropy change = entropy transfer + entropy change. Analyze entropy changes in thermodynamic process and learn how to use thermodynamic tables Examine entropy relationships (Tds relations), entropy relations for ideal gases. Property diagrams involving entropy (T-s and h-s diagrams) In this Chapter, we will: Entrpy.ppt, 10/18/01 pages Entropy – A Property Entropy is a thermodynamic property; it can be viewed as a measure of disorder. i.e. More disorganized a system the higher its entropy. Defined using Clausius inequality where ?Q is the differential heat transfer T is the absolute temperature at the boundary where the heat transfer occurs Clausius inequality is valid for all cycles, reversible and irreversible. Consider a reversible Carnot cycle: Since , i.e. it does not change if you return to the same state, it must be a property, by defintion: Let’s define a thermodynamic property entropy (S), such that True for a Reversible Process only Entropy (cont’d) Since entropy is a thermodynamic property, it has fixed values at a fixed thermodynamic states. Hence, the change, ?S, is determined by the initial and final state. BUT.. The change is = only for a Reversible Process 1 2 reversible process any process T S Consider a cycle, where Process 2-1 is reversible and 1-2 may or may not be reversible Increase of Entropy Principle (YAC- Ch. 6-3) Implications: Entropy, unlike energy, is non-conservative since it is always increasing. The entropy of the universe is continuously increasing, in other words, it is becoming disorgan