核壳结构的合成解答.ppt

The Synthesis of Core/Shell Structure Materials Inorganic NanoParticles 主讲人：林 翰 成 员：马良来 蔡平 王亚杰 张瑜 曹哲瑞 欧阳丽萍 郭宜君 魏冰 李翔 Cover Team No.3 University of Science Technology of China Origin?of?Core/Shell ? bulk?materials single?nanoparticles ??semiconductor?nanoparticles concentric multilayer semiconductor nanoparticles Definition: The?core/shell?type?nanoparticles?can?be?broadly?defined?as?comprising?a?core?(inner?material)?and?a?shell?(outer?layer?material).? Origin Long long ago 1960s 1980s 1990s Publications per year for core/shell nanoparticles during the period 1994 to 2014 (Data collected from Web of Science Database) Classification?of?Core/Shell?Nanoparticles Classification (a) Inorganic/inorganic (b) Inorganic/organic (c) Organic/inorganic (d) Organic/organic Type 1: Classification?based?on?Composition Type 2: Classification?based?on? Geometric (a) Spherical core/shell nanoparticles (b) Hexagonal core/shell nanoparticles (c) Multiple small core materials coated by single shell material (d) Nano-matryushka material (e) Movable core within hollow shell material ?Synthesis?Approaches for?Core/Shell?Nanoparticles? (A) Synthesis the?core?nanoparticles (or SILAR) (B) Cation exchange (C) Solvent-free fabrication of core/shell nanoparticles (D) Gas phase synthesis (E) Preformed clusters in the gas phase Approaches Ⅰ. Chemical Routes Ⅱ. Physical Routes (A) Synthesis?the?core?nanoparticles (or SILAR) 2. Absorbing half of a monolayer by CdO or S, react each other to form a monolayer 1. Synthesis of CdSe Core Nanocrystals 3. Monolayer accumulated to multilayer, which is complete shell Synthesis Steps： 1/5 Monodisperse CdSe/CdS Core/Shell Nanocrystals Using Ion Layer Adsorption and Reaction CdSe (Core) CdS (Shell) Li, J. Jack, et al. Journal of the American Chemical Society 125.41 (2003): 12567-12575. 1. Synthesis of PdSe Core Nanocrystals 2. Exchange cation from the outer layer inwardly 3. Complete shell formed 2/5