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Applications of ICP Etching In Fabrication of Controllable Polymer Nanowires;Zhong Lin Wang;Nanowires :
Sizes, interfacial properties and electronic properties can be precisely controlled during synthesis
Possible to combine different chemical composition in nanoscale
Structures of NWs can be designed to achieve new functions;Polymer nanowires (PNWs)
Potential applications in organic light-emitting diodes (OLEDs), field-effect transistors (FETs) and solar cells
Orientation, dimensionality and location control required (Challenge!!)
;Previous approach:
Anodic aluminum oxide (AAO) template-based technique
Distorted and bunched PNWs after removing the template
Our approach:
Inductively coupled plasma (ICP) etching
Plasma
Highly ionized gas
High chemical reactivity
;Methods to generate plasma;Plasma etching
Key process in large-scale integrated circuit manufacture
Physical and chemical etching process;Improvement (ICP)
Inductive coils are used to create an intense plasma(1015 cm-3)with higher energy
Connect the sample to the RF signal to get a more anisotropic etching
;;Earlier edition;All NWs perpendicular to the substrate
Uniform size and distribution
Not limited by the chemical structures, worked for any organic materials interested;Pattern fabrication
All NWs along the lines scratched by the needle tip
No NWs where were unscratched (flat) ;Proposed mechanism;Improved edition;a. PMMA
b. PS
c. PDMS
d. PEDOT/PSS
e. PEN
f. PET
g. Durafilm
h. Kapton film
i. 4 ×4cm2 Kapton NWs;Pattern control;Density control (why?);Length control;Let’s test it in a real device!!;Summary;References;Appendix;MEH-PPV
poly(2-methoxy, 5-(2’- ethylhexyloxy)-1,4-phenylene vinylene
an optoelectronic polymer for OLEDs and organic solar cells;Thank you for your attention
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