普鲁士蓝薄膜的电沉积及其电致变色性能.docVIP

本科毕业论文 普鲁士蓝薄膜的电沉积及其电致变色性能 所在院系：城市建设与环境工程学院 学生姓名：曹哲超 班级名称：10化学A1 学 号：104865297 专业名称：材料化学（绿色电子材料） 指导教师：王金敏 二○一四年五月  Shanghai Second Polytechnic University (SSPU) Electrodeposition and electrochromic properties of Prussina blue films School/Department: School of Urban Development and Environmental Engineering Student Name: Zhechao Cao Class: 10 Chemical Class A1 Number：104865297 Major: Materials Chemistry Teacher: Jinmin Wang May, 2014  摘要  PAGE \* MERGEFORMAT IV 摘要 普鲁士蓝及其衍生物材料在催化、光学、电磁学、热学、电子学、传感器、力学等方面都表现出不同于传统材料的优异特性，它引起了科学工作者的广泛关注。如能实现对纳米材料颗粒大小、形貌及晶化度等特性的控制合成，必将给这一古老而重要的材料带来一次新的发展生机。在水热反应下，不同反应条件下合成的普鲁士蓝纳米晶颗粒的结构和形貌都不相同。通过比较合成的普鲁士蓝纳米晶颗粒的表征，我们得出在反应条件在pH=1，聚乙烯吡咯烷酮(PVP)的量为3g，铁氰化钾的浓度为0.1mol/L时，所合成的普鲁士蓝纳米晶颗粒表面光滑，结构为立方体单晶结构，普鲁士蓝纳米晶颗粒的尺寸在300-500纳米之间。将合成的普鲁士蓝纳米颗粒在导电玻璃上制成普鲁士蓝薄膜，通过电化学工作站测试了它们的电化学性能。 关键词：普鲁士蓝；薄膜；电致变色；  Abstract Abstract Prussian blue and its derivatives materials in catalysis, optics, electromagnetism, thermology, electronics, sensors, mechanical showed excellent properties of different from traditional materials, it caused the? wide attention of scientific workers . If you can realize the nano material particle size, morphology and crystallization degree of features such as control, will certainly give this ancient and important material to bring a new vitality for development. In the hydrothermal reaction, structure and morphology of the synthesized under different reaction conditions Prussian Blue nanocrystalline particles are not the same. Comparing by characterizing Prussian Blue nannoparticles, we know when pH=1, PVP=3g, K3Fe(CN)6=0.1mol/L, the synthesis of Prussian blue nanocrystalline particles surface are smooth, the size of the particles of Prussian Blue nanocrystals between 300-500 nanometers. The synthesis of Prus