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学科文献信息

学科文献信息 化工专题(ScienceDirect数据库) 第期 (总期) 2016年月日 (请把光标放在文献题名上,按住Crtl键单击题名可打开文献全文) Cobalt-nitrogen-doped ordered macro-/mesoporous carbon for highly efficient oxygen reduction reaction Pages 1-8 Tingting Sun, Lianbin Xu, Shengyu Li, Wenxia Chai, Yan Huang, Yushan Yan, Jianfeng Chen Abstract Cobalt-nitrogen-doped three-dimensionally 3D ordered macro-/mesoporous carbons Co-N-OMMCs have been fabricated through a dual-templating synthesis approach in a one-pot controllable procedure by the use of silica colloidal crystal opal as a macroporous mold and triblock copolymer Pluronic F127 as a mesoporous template. The optimal catalyst Co-N-OMMC-0.6 exhibits comparable catalytic activity but much higher durability and tolerance of methanol in comparison with the commercial 20爓t% Pt/C catalyst for oxygen reduction reaction ORR in an alkaline medium. The remarkable ORR electrocatalytic performance of the Co-N-OMMC-0.6 is ascribed to the homogeneous distribution of abundant Co-Nxactive sites, as well as the large surface area and efficient mass/charge transport from the unique structure combining well-ordered bicontinuous mesopores with 3D interconnected periodic macropores. Iron incorporation on graphene nanoflakes for the synthesis of a non-noble metal fuel cell catalyst Pages 9-15 Pierre-Alexandre Pascone, Jasmin de Campos, Jean-Luc Meunier, Dimitrios Berk Abstract In the present work, graphene nanoflakes GNFs were grown at both low and high levels of nitrogen functionalization and subsequently put through a wet-chemical method to add iron functionalities to the surface and create active catalyst centers. No mechanical treatments are used in order to minimize the formation of defects on the GNFs and evaluate if iron-nitrogen-GNF edges or surface sites can generate catalytic activity rather than the macropore structures holding these functionalities on porous carbon black. The catalysts produced under various synthesis routes were characterized and screened for th

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