岛津GCMS-TQ8040教材.ppt

This is the example of EI spectra. The upper is for Benzene. The base peak is the molecular ion 78 The lower is for Acetone The base peak is the fragment ion 43 The next is the chemical ionization method In CI, reagent gas is required for ionization. Since CI can be occurred at more than about 10Pa of ion source pressure, the ion source is closed type . The feature of CI is the ionization with less fragmentation, we call such an ionization “ soft ionization”. In the CI ，pseudo -molecular ions tend to be generated. The pseudo-molecular ion is the ion such that a proton ion H+ is added to sam