材料研究方法(英文陈述).pptxVIP

THE APPLICATION OF AFM ON THE MICROPHASE SEPARATION OF POLYURETHANE Pengfei Li 25th Apr,2014 CONTENT Introduction of PU Principle of AFM Application of AFM POLYURETHANE What is polyurethane? MDI HDI IPDI PEG HO(CH2CH2O)nH PPG PTHF POLYURETHANE Different Structures(Thermodynamic incompatible) ——Phase separation structures——test methods What can AFM do ? AFM INSTRUMENT: Atomic Force Microscope PRINCIPLE: a cantilever with a sharp tip is used to scan the specimen surface,and When the tip is brought into proximity of a sample surface, forces between the tip and the sample lead to a deflection of the cantilever according to Hook’law.So,forces that are measured and chang into the height of the sample surface. What Can We Get From The AFM? Contact mode The tip drag across the surface Tapping mode keeping the probe tip close enough to the sample preventing the tip from sticking to the surface Increase amplitude Non-contact mode cantilever does not contact the sample surface TEM AFM TPU TPU with 0.05wt%ZnO Which one has lager degree of phase separation? 200nm. Same height 200nm. Same force 500nm. 3D picture of PU Valley Soft segment Peak Hard segment THANK YOU The AFM consists of a cantilever with a sharp tip (probe) at its end that is used to scan the specimen surface. The cantilever is typically silicon or silicon nitride with a tip radius of curvature on the order of nanometers. When the tip is brought into proximity of a sample surface, forces between the tip and the sample lead to a deflection of the cantilever according to Hookes law.[2] Depending on the situation, forces that are measured in AFM include mechanical contact force, van der Waals forces, capillary forces, chemical bonding, electrostatic forces, magnetic forces (see magnetic force microscope, MFM), Casimir forces, solvation forces Segmented polyurethanes (PUs) have a great application potential due to their wide range of