危险物品处理.ppt

Training duration: 2 hours Who need to participate the training: All offshore staff; warehouse staff; shipping staff. MSDSNFPA labels Chemical storage handling, Radioactive source handling, NORMs PPE Waste types, Waste segregation, Waste disposal Course Learning Objectives Upon completion of this course you will be able to: Know H2S chemical and physical character and hazards; Know H2S PEL, STEL and IDLH concentration; Know how to react to the above concentration/Emergency response; Know H2S rescue/first aid H?S Character (what is H2S) Highly toxic, colorless gas, heavier than air, with the odor of rotten eggs. It burns with a blue flame and produces SO? which is very irritating gas with a pungent odor. H?S Character Explosion range: mixture 4.3% to 45% by volume in air H?S is incompatible with some oxidizing agents, such as nitric acid and chlorine tri-fluoride, and may react violently or ignite spontaneously Ignition temperature 149°C Water soluble 4 volumes gas in 1 volume water in 0°C H?S Hazards Occupational Exposure Limit (OEL) Routes of exposure Inhalation Contact Where H?S MAY Occur offshore? For FPSO Gas Flotation Unit De-Oiling Tanks Slop Tank Cargo Tanks When open process For WHPs Drilling rig STU/open close drain When open process How H?S appear at here? No evidence shows that H?S come from our oil reservoir / formation till now Suspect biologic bacteria occurred and accumulated in down hole fluids produced the H?S Detection of H?S Your nose is usually the first and unfortunately, sometime the last Your nose can detect as little as 0.13 PPM H?S The sense of smell will be deadened in 2-3 minutes if H?S in 100 PPM -150 PPM range. Your smell sense become bluntness if you long time contact low concentration H?S gas. IMPORTANT YOU CAN NOT RELY ON YOUR NOSE TO TELL YOU HOW MUCH H?S GAS IS PRESENT YOU CAN NOT DETECT H?S BY YOUR NOSE DOES NOT MEAN THERE IS NO H?S Detection of H?S Air Sampling Gas Detector Tubes The concentration of H?S is regist