PBO纤维.docVIP

毕业设计（论文） 题 目： 常见试剂及等离子体处理对PBO纤 维性能影响的探究 学 院： 纺织与材料学院 专业班级： 轻化工程 08级（2）班 指导教师： 谭艳君 职称： 高工 学生姓名： 田习菲 学 号： 40801030232 摘 要 聚对苯撑苯并二噁唑（PBO)纤维是由PBO聚合物通过液晶纺丝技术制得的一种高性能纤维与其它高性能纤维相比，PBO纤维具有更高的比强度、比模量和耐热性阻燃性，因此被誉为“21世纪的超级纤维”。但PBO纤维表面光滑，且呈化学惰性，与树脂基体间的界面粘接性能很差，这极大影响了纤维力学性能的充分发挥，严重制约了PBO纤维在高性能复合材料领域中的应用。因此，改善PBO纤维的表面性能、提高它与树脂基体间的界面粘结性能是PBO纤维得以在高性能复合材料领域中广泛应用的关键。 本课题分别采用低温等离子体及常见化学试剂对PBO纤维进行处理，其中在低温等离子体处理中，分别通过处理时间以及处理功率的改变来研究其对纤维性能的影响。通过单纤维拉伸测试分析了等离子体处理及化学试剂处理对纤维力学性能的影响；通过SEM观察纤维表面形态的变化并通过显微镜观察纤维横截面的变化；通过IR分析纤维表面元素组成及基团的变化。 PBO纤维，等离子体处理，表面性能 ABSTRACT Poly( P-Phenylene benzobisoxazole ) ( PBO ) fiber is a kind of high Performance fiber obtained by liquid crystal spinning through PBO polymer. PBO fiber is called the super fiber in the 21st century， for its excellent properties such as higher special strength and modulus, heat resistant and flame retardant than other high-Performance fibers . It can be used to produce high-performance composite materials in aeronautics, and national defense and other high-tech fields.However，the relatively smooth and chemically in active surface，induce the poor adhesion property between PBO and resin matrix , and enormously affect the fiber mechanic performances to fully display in composites, thus seriously restrict applications of PBO fiber in high-performance composite material fields.Therefor，the improvements of PBO fiber surface properties and adhesion properties between PBO and resin matrix are the keys for it to be applied in the domain of high performance composite materials. At present , there are many ways for modifying PBO fiber surface , such as chemistry modification ,radiation modification and plasma modification ,etc. Plasma modification is a perfect method among them with the advantage that the modification only affects the outer most layers of a substrate without damaging the