气凝胶的性质和生产.ppt

Characterization（Optical Properties） The intrinsic absorbance is low in the visible region. Weak absorbances begin to appear in the near infrared, cuts off transmission around 2700-3200 nm The Si-O-Si fundamental vibration ~1100 cm-1 O-H stretching vibrations ~3500 cm-1 Characterization（Thermal Properties） Carbon is an effective absorber of infrared radiation trap space dust particles aboard the Stardust spacecraft 0 1 2 3 4 0 1 2 3 4 * * * * * Material Synthetic Chemistry PPT Presentation Group 29 5 4 3 A Heavyweight Guest will Attend the PPT Competition ACADEMIC NEWS AND GOSSIP WORLD EXCLUSIVES THE USTC NEWS The ppt competition of the class “material synthetic chemistry” is held in 5204，building 5，USTC today. Students from different majors are ready to give wonderful reports. A heavyweight guest will also attend this competition. Who will it be？ Let’s wait and see! 2010.12.29 Aerogel What’s the lightest solid material in the world？ Aerogel a?manufactured?material with the lowest bulk?density?of any known porous?solid.? derived from a?gel in which the?liquid?component of the gel has been replaced with a?gas. It is nicknamed?frozen smoke,solid smoke,?solid air?or blue smoke? Introduction in the 1968,A French called Teichner found a better synthetic process, namely sol-gel method using TMOS,replacing the sodium silicate used by Kistler with an alkoxysilane. History The first aerogel has been created in 1931 by Steven Kistler, due to a bet made with Charles Learned over who would be able to replace the liquid state into a jelly-like substance with gas, without reducing its original Volume Aerogel: More than 99% gas Less than 1% solid in volume The density can be as low as 0.003g/cm3 Types 1.Silica Aerogel most common strongly absorbs?infrared?radiation remarkable thermal insulative properties 2.Carbon Aerogel high?porosity ，high surface area 3.Aliumina Aerogel used as catalysts ，do