04 - UNSTEADY STATE DIFFUSION.pptVIP

UNSTEADY STATE DIFFUSION MASS TRANSFER MODEL CONTROL VOLUME FIG. 7.1-1 TOTAL DIFFERENTIAL MODEL SIMPLIFICATIONS CONSTANT SOLUTION DENSITY, ρ NO CHEMICAL REACTION, R = 0 NO CONVECTION TERMS MODEL SIMPLIFICATIONS SINGLE DIMENSIONAL FLOW GENERAL SOLUTIONS (SECTION 5.3) USE DIMENSIONLESS CONCENTRATIONS REQUIRE BOUNDARY AND INITIAL CONDITIONS MODEL SOLUTIONS USE SEPARATION OF VARIABLES INFINITE SERIES SOLUTIONS GEOMETRY DEPENDENT SLAB [SEE (5.3-6)] HEAT TRANSFER ANALOGS CORRELATION TABLE INTERFACE CONDITIONS IMPACT, K RESULTS IN CHARTS SEE FIGURES IN SECTION 5.3 Larrauri, Ruperez, and Saura-Calixto, Effect of Drying Temperature on the Stability of Polyphenols and Antioxidant Activity of Red Grape Pomace Peels, J. Agric. Food Chem., 45 (4), 1390 -1393, 1997 RAISIN DRYING PROCESS http://www.fcps.k12.va.us/fs/food/images/raisins.jpg SIMULATION OUTPUT TYPICAL TWO DIMENSIONAL OUTPUT TRANSIENT STEADY STATE MULTI-DIMENSIONAL MODELS USE PRINCIPLE OF SUPERPOSITION MASS TRANSFER COEFFCIENTS CONCENTRATION DRIVING FORCE MOLECULAR IN LAMINAR REGION TURBULENT TRANSITION DRIVING FORCES MASS OR MOLE FRACTIONS CONCENTRATIONS PARTIAL PRESSURES TRANSFER COEFFICIENTS GENERAL FORM EQUIMOLAR VARIOUS UNITS – GASES SIMILAR EQUATIONS FOR LIQUIDS TRANSFER COEFFICIENTS UNICOMPONENT RELATIONSHIP k AND D CORRELATION SUMMARY TABLE 7.2-1 UNITS MUST BE CONSISTENT FILM THEORY MODEL ALL RESISTANCE IS IN FILM K = k(D1) Treybal, Mass Transfer Operations, McGraw-Hill,1968, Chapter 3. HIGH FLUX DIFFUSION-INDUCED CONVECTION MODIFIED k VALUES FOR FILM THEORY HIGH FLUX EXAMPLE H. D. Doan* and M. E. Fayed, 1039 -1047, 2000 H. D. Doan* and M. E. Fayed, Entrance Effect and Gas-Film Mass-Transfer Coefficient in a Large-Diameter Packed Column, Ind. Eng. Chem. Res., 39 (4), 1039 -1047, 2000