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FUEL CELLS – DIRECT ALCOHOL FUEL CELLS Direct Ethanol Fuel Cells
FUEL CELLS - DIRECT ALCOHOL FUEL CELLS
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Overview
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References and further reading may be available for this article. To view references and further reading you must purchase this article.
T.S. Zhaoa, Z.X. Lianga and J.B. Xua
a The Hong Kong University of Science and Technology, Kowloon, Hong Kong SAR, China
Available online 23 November 2009.
Abstract
Direct alcohol fuel cells (DAFCs) are a type of electrochemical energy conversion device that directly convert the chemical energy stored in a liquid alcohol fuel, commonly methanol but also ethanol, ethylene glycol, or n-propanol, to electricity. Because of their simplicity, high energy density, instantaneous recharging, and presumably long life, DAFCs have been identified as the most promising candidate to replace batteries in micropower applications. This article presents an overview of DAFC technology, including its working principle, features, challenges, and application opportunities.
Author Keywords: Direct alcohol fuel cells; Direct ethanol fuel cells; Direct methanol fuel cells
Nomenclature
Symbols and Units
A
area of the PEM
Ci
alcohol concentration at the interface between the anode and the PEM
Dm
diffusion constant of the alcohol in the PEM
Er°
reversible cell potential
Esp
theoretical energy density
F
Faraday constant
Icr
equivalent current density of alcohol crossover
Mw
fuel molecular weight
n
number of electrons involved
z
number of electrons transferred
xi
mole fraction of alcohol in solution
δm
thickness of the PEM
ΔG°
Gibbs free energy change for overall reaction
η
theoretical energy conversion efficiency
ξ
electroosmotic coefficient
Abbreviations and Acronyms
FUEL CELLS - DIRECT ALCOHOL FUEL CELLS
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Modeling
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References and further reading may be available for this article. To view references and further reading you must purchase this article.
T.S. Zhaoa and W.W. Yanga
a The Hong Kong University of Science and Technology, Kowloon, Hong Kong SAR, Peoples Repu
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