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摘要 铜的氧族化合物由于有许多特殊的光电性质,是一类重要的新型无机功能材料,成为近年来的研究热点。目前已有很多报到关于有效合成各种形貌CuO,Cu2O,如纳米颗粒,纳米棒,纳米片,纳米管状等等。但对于同属于铜的氧族化合物的Cu_2S的合成和性质研究却较少,Cu2S是一种p型半导体,禁带宽度约1.2eV,它已在太阳能电池、显示器的薄膜晶体管、光电子切片、生物传感器等方面有所应用,因此它是一种有潜力的半导体材料。 本文采用高温合成了形貌可控制的Cu2S纳米结构,应用X-射线衍射(XRD)、X-射线原子吸收光谱(XPS)、扫描电子显微镜(SEM)、高倍透射电子显微镜(TEM)、比表面分析(BET)等测试手段分别对所得材料的结构形貌进行表征分析;并通过荧光光谱测试对纳米结构的光学性质进行了表征分析。对所合成材料的生长机理以及其发光原理进行了分析讨论,给出了一些合理的解释并得到了一些有意义的结论。 实验结果表明,在不同反应条件下,可以控制合成不同形貌的Cu_2S纳米材料,如阵列状、纳米花状、纳米颗粒状、纳米管状等。紫外-可见吸收光谱(UV-Vis)显示该类材料吸收发生了蓝移,计算得到的禁带宽度值增大。纳米花状Cu_2S BET结果显示其平均孔径为35nm左右,是一种良好的介孔材料。通过荧光光谱分析研究了其发光性能,在250nm的长波紫外激发下其发射范围在530-560nm的黄绿光,并且,峰的范围和强度取决于材料的形貌。另外,由于花状Cu_2S的特殊形貌,对有机染料活性艳红(X-3B)有较高的光催化活性,在100min内降解活性艳红的效率高达50.1%。Cu_2S,纳米阵列 Abstract Copper oxygen compounds because there are many special photoelectric properties, the family is a kind of important new type of inorganic functional materials, become a research hotspot in recent years. There are many report about effective synthesis of various morphology CuO, Cu2O, such as nanoparticles, nanorods, nano film, nano tube and so on. But for the same copper Cu_2S chalcogen compounds are less, the study of the synthesis and properties of Cu2S is a p-type semiconductor, forbidden band width is about 1.2 eV, it has been in solar cells, display of the thin film transistor, photoelectron slice, biological sensors application, so it is a kind of semiconductor materials have potential. This paper synthesized by high temperature gas solid morphology controllable Cu2S nanowires array structure, application of X-ray diffraction (XRD), X-ray atomic absorption spectroscopy (XPS), scanning electron microscope (SEM), transmission electron microscopy at high magnification (TEM), specific surface analysis (BET) test means such as morphology of the obtained materials were characterized respectively analysis; And through the fluorescence spectrum test analysis on the optical properties of the nano structures have been characterized. On the growth mechanism of composite materials and