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林建超32-33-A16
Historical Insight
The motion of large objects, such as planets and satellites, can be predicted to a high
degree of accuracy using classical theoretical physicsbased on Newton’s laws of mo-
tion. Beginning around 1895, certain experimental results that involved electrons and
high-frequency electromagnetic waves (x-rays) appeared to be inconsistent with re-
sults predicted by classical physics .In 1923, Arthur Compton established that x-rays
behave like particles with well-defined energy quanta when they scatter from metals.
These new experimental results can be predicted and described using the principles of
quantum mechanics, which were developed during the 1920s. The quantum mechan-
Ical wave theory is the basis for the theory of semiconductor physics.
Present-Day Insight
Quantum mechanical wave theory is still the basis for describing and predicting the
Behavior of semiconductor devices and materials.Quantum mechanics is especially
important in analyzing heterojunction lasers (Chapter 12).
2.1 | PRINCIPLES OF QUANTUM MECHANICS
Objective:Discuss a few basic principles of quantum mechanics that apply to
semiconductor material and device physics.
We are ultimately interested in semiconductor materials whose electrical properties
are directly related to the behavior of electrons in the crystal lattice. The behavior and
characteristics of these electrons can be described by the formulation of quantum
mechanics called wave mechanics. We first describe two principles of quantum me-
chanics. We then briefly introduce Schrodinger’s wave equation and consider a few
basic results that are derived from applying this equation to specific problems.
2.1.1 Energy Quanta
One experiment that demonstrates an inconsistency-between experimental results
and the classical theory of light is called the photoelectric effect. If monochromatic
light is incident on a clean surface of a material, then under certain conditions, elec-
trons (photoelectrons) are emitted from the sur
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