HNMR.ppt

* * 20 19 19 19 1 * * 6 6 1 * * * * * * * * * * * * * * 21 21 * * * * * * * * 3 7 7 10 11 1 1 19 22 23 1 1 11 11 11 6 21 21 25 * * * dd J=7.7, 1.5 dd J=8.1, 0.7 td J=7.4, 1.1 ~td J=8.1, 1.5 Aromatic substituent pattern 1 Calculated shifts ?1 = 8.31 ?2 = 7.74 ?1 = 7.69 ?1 = 8.08 C5H9NO4 1H 2H 3H 3H CH3 CH2 t O q C O CH CH3 NO2 d q C5H8O CHO, d J=8.1 Hz dt, J=15.8, 6.9 CHO CH ddt, J=15.8, 8.1, 1.5 t, J=7.4 CH CH2 CH3 CH2 Trans J 2Jgem = 1.5 C4H6O2 CH3 C s CH= dd 14.0, 6.6 O O C C H H H dd 14.0, 1.5 Jtrans = 14.0 Jcis = 6.6 dd 6.6, 1.5 80 MHz 400 MHz 3 3, d(2.4) 5 5, dd 9.2, 2.4 6 6,