08-Hydrogen Storage materials.pptVIP

Tel: 0571- 8795 1152 Email: lxchen@zju.edu.cn Laboratory of Hydrogen Storage Materials Institute of Metallic Materials Zhejiang University Hydrogen Storage Materials Dr. Li-xin Chen Kinetics for Hydriding / dehydriding of Hydrogen Storage Alloys Lecture VII 1.1 Experimental procedures 1) Reactor design (1) Purpose: Reducing the effects of heat and keeping constant temperature of reaction system. (2) Methods: I . Kinetics for hydriding/dehydriding of HSAs in gas-solid reaction ① Increasing the contact surface; ② Decreasing the amount of HSA powders; ③ Improving the heat transferability. (3) Development of reactor ① Autoclave reactor (第一代高压釜式反应器) Features: larger amount of sample powders; 1.1 Experimental procedures small contact surface. HSA ② Thin discal reactor Features: sample powders ↓; 1.1 Experimental procedures heat transferability ↑; thermal flow in only one direction. Temp. controlling system HSA ③ Double-wall reactor Features: 1.1 Experimental procedures sample powders ↓↓; heat transferability ↑↑, ΔT 1℃. HSA Temp. controlling system 2) Experimental methods (1) Isochoric method (等容法) Features: 1.1 Experimental procedures easily monitoring pressure change; 1.1 Experimental procedures controllability of initial pressure for targeting a given final composition; suitable for studying HSAs with one phase in solid solution region; unsuitable for studying the reaction kinetics with respect to phase transformation. Because hydrogenation process includes solid solution and phase transformation, it is hardly distinguished. (2) Isobaric method (等压法) 1.1 Experimental procedures 1.1 Experimental procedures Features: easily for detailed analysis of the experimental data; suitable for studying HSAs with two phases in phase transformation region; unsuitable for studying HSAs with one phase in solid solution region. (3) Isothermal method (等温法, on a double-wall reactor) 1.1 Experimental