DSC应用.docVIP

1：聚苯乙烯的玻璃化转变 Glass transition of polystyrene 样品Sample Styron 683 条件 测试仪器：DSC Measuring cell : DSC Conditions 坩埚：40l标准铝坩埚，钻孔盖 Pan:Aluminum standard 40l, pierced lid ? 样品制备：从球状颗粒上切出圆片，12 mg Sample preparation:Disk cut from pellet, 12mg ? DSC测试：第一轮加热以10 K/min从30至250°C，在自动进样器中骤冷至室温，第二轮加热以10 K/min从30°C加热至250°C DSC measurement:First heating run from 30 to 250?C at 10K/min, quench-cooled to room temperature in the sample changer, second heating run from 30 to 250?C at 10K/min. ? 气氛：氮气，50 cm3/min Atmosphere : Nitrogen, 50 cm3/min ? ? ? ? ? 计算Evaluation 第一轮没有计算，因为由于热历史效应而有变形。第二轮用玻璃化转变显示结果及其他信息。转变相当清晰(起始点与终点只有7K，范围很小)。比热的变化为0.32 J/gK。 The first run has not been evaluated because it is distorted due to the effects of thermal history. The second run shows the results and additional information given by the glass transition evaluation. The transition is quite sharp (indicated by the small range of 7K between onset and end point). The change of the specific heat capacity is 0.32J/gK. 解释Interpretation 聚苯乙烯，至少市售的无规型，是完全无定形的。它的玻璃化转变温度约为100°C。通常第一轮加热曲线由于松驰过程而在玻璃化转变区是不规则的。第二轮加热由于没有热历史，生成正常的玻璃化转变曲线。 Polystyrene, at least the commercially available atactic type, is entirely amorphous. Its glass transition temperature is approx. 100?C. Usually the first heating run gives a curve in which the region around the glass transition is distorted due to relaxation processes. The second heating run without the thermal history yields the normal shape of a glass transition. 结论Conclusion 应该对第二轮加热进行数据计算。 The evaluation should be performed on the second heating run. 回顶端 2：等温固化的DSC测量 Isothermal curing by DSC 目的Purpose 研究热固性体系的等温固化行为并直接计算等温转化率曲线。 To study the isothermal curing behavior of a thermosetting system and calculate the isothermal conversion curve directly. 样品Sample 以活性基团化学计量比混合的由DGEBA和DDM组成的环氧树脂体系。 Epoxy resin system consisting of DGEBA and DDM mixed in the stoichiometric ratio of the reactive groups. 条件 测试仪器：DSC Measuring cell:DSC Conditions