Chapter 6 Arenes and Aromaticity.pptVIP

Limitation to Friedel-Crafts Reactions: Friedel-Crafts reactions do not occur when powerful electron-drawing groups are present on the aromatic ring. -NO2, -SO3H, RCO-,-COOH, -NR3 ect.. + Preparation of unbranched alkyl benzene: Application of acylation to aromatic ring 1-Pheny-1-butanone (1-苯基1-丁酮)(86%) Chapter 6 Arenes and Aromaticity 6.1 The Structure of Benzene 1. A resonance theory 2. An orbital hybridization view 3. The molecular obitals 6.2 Nomenclature of Benzene Derivatives 6.3 Aromaticity and the Huckel(4n + 2)rule 6.3.1 Annulenes(轮烯)