ABriefIntroductionofOrganicMagneticMaterials.pptVIP

A Brief Introduction of Polymeric Magnetic Materials Hua-Qiao,Peng 2006.06.07 After compass comes into being,magnetic materials undergo a very long time to develop. Tranditional inorganic magnetic materials’ disadvantages: 1.High relative density over 4.0 . 2.High magnetic loss. 3.Dramatic change of magnetic properties with temperature. The scientist in Japan who finds polymer’s conductivity win the Nobel prize.So why not polymer can have magnetism ferrite inorganic rare earth Magnetic materials composite polymeric organic structure organometallic Advantages: 1.Low relative densities 2.Ease of processing 3.Stable magnetic properties 4.Variability in structure Miller,Esptein,Ovchinnikov,Sugano,Palacio,Lin America Russia Japan Spain China Ovchinnikov designed and synthesized a novel structure polymeric magnetic materials. Ovchinnikov et al.Nature,1987,326:370. Liang synthesized [Co pzca 2 H2O ]n, [Co pzca 2 H2O ]n. pzca 2-pyrazinecarboxylate Both of the two compounds show faint magnetism. Xu synthesized [Cu phen H2O 2 SO4 ]n. phen 1,10-phenanthroline It displays magnetism. Liang Y C et al,Inorganica Chimica Acta,2002,328:152~158. Xu L et al,Inorganic Chemistry Communications,2003,6:740~743. Miller synthesized a series of ferrocene-TCNE magnetic materials and investigated the magnetic mechanism in detail.But the magnetic mechanism was not very clear. Miller J S,et al New Scientist,1990,6:23. Kahn and Gleizes synthesize some polymeric magnetic materials containing Cu,Mn,Ni. Kahn, et al.J Am Chem Soc,1988,110:782. Gleizes, et al.J Am Chem Soc,1984,106,3727. From 1950,schiff alkali organometallic magnetic materials have received more and more interest. Lions and Martin coordinated ferric sulfate with a compound containing nitrogen to synthesize a new compound [ Fe C13H17N3 2 SO4·6H2O]n , namely, PPH-FeSO4 and find that it shows magnetism under normal temperature. Lions F,Martin K V,J Chem Soc Jan,1957,79:2733. In a word,structural type of polymeric magne