Known Nitrides and synthesis1.pptVIP

Known Nitrides and synthesis methods that could be adopted nitrides of main group elements nitrides of main group elements Mg3N2: reactant for synthesising other nitrides, special ceramic materials, foaming agent for fabricating special alloys, special glass, catalyst, retrieve nuclear waste, vaccum packaging materials, additives in smelting high strength steel. Si3N4: ceramic materials with excellent physical properties; potential in making radiator in integrated circuit, high efficient ion capacitor and nitrogen detector; nonlinear optical materials, inoganic phosphors. others like GeN, Ca3N2, Sn3N4, Se4N4 and so on. nitrides of transition metals nitrides of transition metals nitrides of transition metals Zr3N4: refractory materials with high melting points, has an outstanding wear resistance with respect to the machining of lowcarbon steels, superior oxidation resistance, high hot hardness, relatively low residual stress and low thermal conductivity others like NbN, W2N, PtN, IrN, Hf3N4, Co3N, Ni3N and so on. Nonaqueous solvothermal chemical reactions slowly heated: room temperature to 50°C 1~2°C/min, hold for 4 h , then to 100°C hold for 10~12 h , subsequent temperature increases in 5~10 °C increments were made over several days ~40 °C/day for toluene time: 3-5 days Two-stage aerosol synthesis Mesoporous graphitic carbon nitride as an nanoreactor Dry autoclaving or solid-state metathesis Instrumetation: a reactor Haynes 230 alloy surrounded by a heater. The reactor: an inner lining of quartz tube, a pressure gauge, and piping for purging desired gases. sustain under the autogenic self-produced pressure of the dissociated chemical molecule s at elevated temperatures. Sol-gel The urea-glass route The urea-glass route * LOGO * LOGO * LOGO * LOGO Wan Jun 2011.12.30 nitrides of main group elements 1 nitrides of transition metals 2 Nitrides that have been fabricated BN C3N4 Li3N electrical insulator and heat-resistant material, information storage