Low Temperature Oxidation Experiments and Kinetics Model of Heavy Oil.docVIP

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Low Temperature Oxidation Experiments and Kinetics Model of Heavy Oil.doc

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Low Temperature Oxidation Experiments and Kinetics Model of Heavy Oil.doc

Low Temperature Oxidation Experiments and Kinetics Model of Heavy Oil 　　Abstract 　　Air injection is an effective technique for improved oil recovery. For a typical heavy oil sample， the effects of temperature on the oxidation characteristics were studied by low temperature oxidation （LTO） experiments. Kinetic parameters such as activation energy， frequency factor （pre-exponential factor） and reaction order are determined by using Arrhenius Equation. These parameters provide a theoretical basis for numerical simulation of LTO taking place during air injection in heavy oil reservoirs. The results of LTO experiments show that heavy oil has good low temperature oxidation properties and LTO reaction rate is mainly related to temperature， oxygen partial pressure and properties of crude oil. In the experimental temperature range， the oxidation reaction can effectively consume oxygen and at the same time produce large amount of CO2. 　　Key words： Air injection； Low temperature oxidation； Kinetics model （70-150 oC）　　Chen， Z.Y.， Wang， L.， Tang， L.Z.， Huang， A.Y. （2012）. Low Temperature Oxidation Experiments and Kinetics Model of Heavy Oil. Advances in Petroleum Exploration and Development， 4（2）， -0. Available from： http：///index.php/aped/article/view/j.aped.1925543820120402.792 　　DOI： http：///10.3968/j.aped.1925543820120402.792 　　INTRODUCTION 　　Air injection is an effective technique for improved oil recovery （Greaves et al.， 2000； Greaves et al.， 1999）. Air injection process has been proven to be an effective improved oil recovery technique， which is typically suitable as a secondary oil recovery method for deep reservoirs with very low permeability and poor water injectivity （Yu et al.， 2008； Yu Yang et al.， 2008； Zhao et al.， 2005）. Air injection is currently considered by many operators for a better recovery. 　　The reactions of hydrocarbon with oxygen in an oil reservoir can be classified into low temperature oxidation and high temperature oxidation （HTO， al